JEE MainChemistryBiomoleculesMCQ+4 / −1
Which of the following is the correct structure of L-Glucose?
- A

- B

- C

- D

View written solutionFree
Correct answer: D
-
Key idea: D/L notation for sugars
For monosaccharides, the symbols D and L are assigned by comparing the configuration of the chiral carbon farthest from the carbonyl group with that of glyceraldehyde.
- In an aldohexose like glucose, this is C-5.
- If the on is on the right in Fischer projection, it is D.
- If the on is on the left, it is L.
-
Recall the Fischer projection of D-glucose
The arrangement from to in D-glucose is:
-
Obtain L-glucose from D-glucose
L-glucose is the enantiomer of D-glucose, so every chiral center is inverted.
Therefore, for L-glucose, the positions from to become:
-
How to identify the correct option
So the correct Fischer projection of L-glucose must have:
- aldehyde group () at the top,
- at the bottom,
- and pattern from to as:
-
Comparison with the stored answer
The stored correct answer is D. This matches the structure expected for L-glucose.
Hence, the correct option is D.
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