JEE MainChemistryBiomoleculesMCQ+4 / −1
Match items of Row I with those of Row II. Row I :
Row II : (i) ---(ii) -D--Fructofuranose (iii) -D- Glucopyranose (iv) -D--Glucopyranose Correct match is
Row II : (i) ---(ii) -D--Fructofuranose (iii) -D- Glucopyranose (iv) -D--Glucopyranose Correct match is- AA iii, B iv, C i, D ii
- BA iv, B iii, C i, D ii
- CA i, B ii, C iii, D iv
- DA iii, B iv, C ii, D i
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Correct answer: A
To solve this matching question, we identify the Haworth projection features of each sugar form.
1. Key rule for and forms
For D-sugars in Haworth form:
- The terminal group is generally up.
- -anomer: anomeric is down.
- -anomer: anomeric is up.
2. Identify anomeric carbon
- In glucose (an aldose), the anomeric carbon is C-1.
- In fructose (a ketose), the anomeric carbon is C-2.
3. Distinguish pyranose and furanose
- Glucopyranose has a six-membered ring.
- Fructofuranose has a five-membered ring.
So:
- Structures with 5-membered ring correspond to fructofuranose.
- Structures with 6-membered ring correspond to glucopyranose.
4. Match the four entries
Given Row I:
- -D--Fructofuranose
- -D--Fructofuranose
- -D--Glucopyranose
- -D--Glucopyranose
Now using the standard Haworth criteria:
- A must be -D-glucopyranose iii
- B must be -D-glucopyranose iv
- C must be -D-fructofuranose i
- D must be -D-fructofuranose ii
Thus the correct matching is:
5. Compare with options
This corresponds to Option A.
6. Verification with stored answer
Stored correct answer = A
Our derived answer = A
Hence, they agree.
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