JEE MainChemistryBiomoleculesMCQ+4 / −1
A polysaccharide 'X' on boiling with dil at 393 K under 2-3 atm pressure yields 'Y'. 'Y' on treatment with bromine water gives gluconic acid. 'X' contains -glycosidic linkages only. Compound 'X' is :
- Astarch
- Bcellulose
- Camylose
- Damylopectin
View written solutionFree
Correct answer: B
-
Identify compound from the bromine water test
Bromine water oxidizes an aldehyde group of an aldose to the corresponding aldonic acid.
Since gives gluconic acid on treatment with bromine water, must be glucose.
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Determine what polysaccharide gives on hydrolysis
The question says that polysaccharide on boiling with dilute gives .
Since , must be a polymer of glucose.
-
Use the nature of glycosidic linkage
The question further states that contains only -glycosidic linkages.
Now examine the options:
- Starch: polymer of -D-glucose; contains -linkages
- Amylose: component of starch; has linkages
- Amylopectin: has and linkages
- Cellulose: polymer of -D-glucose; has only glycosidic linkages
-
Match all conditions
Cellulose satisfies both conditions:
- On hydrolysis, it gives glucose
- It contains only -glycosidic linkages
-
Evaluate options
- A: starch incorrect
- B: cellulose correct
- C: amylose incorrect
- D: amylopectin incorrect
Therefore, the compound is:
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