Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Biomolecules question

2022 · 24 Jun · Shift 1 · Q11
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Biomolecules
  5. /2022 · 24 Jun · Shift 1 · Q11

Biomolecules question

2022 · 24 Jun · Shift 1 · Q11

JEE MainChemistryBiomoleculesMCQ+4 / −1
A polysaccharide 'X' on boiling with dil H2SO4H_2SO_4H2​SO4​ at 393 K under 2-3 atm pressure yields 'Y'. 'Y' on treatment with bromine water gives gluconic acid. 'X' contains β\betaβ-glycosidic linkages only. Compound 'X' is :
  1. A
    starch
  2. B
    cellulose
  3. C
    amylose
  4. D
    amylopectin
View written solutionFree

Correct answer: B

  1. Identify compound YYY from the bromine water test

    Bromine water oxidizes an aldehyde group of an aldose to the corresponding aldonic acid.

    Since YYY gives gluconic acid on treatment with bromine water, YYY must be glucose.

    Glucose→Br2/H2OGluconic acid\text{Glucose} \xrightarrow{Br_2/H_2O} \text{Gluconic acid}GlucoseBr2​/H2​O​Gluconic acid

  2. Determine what polysaccharide XXX gives on hydrolysis

    The question says that polysaccharide XXX on boiling with dilute H2SO4H_2SO_4H2​SO4​ gives YYY.

    Since Y=glucoseY = \text{glucose}Y=glucose, XXX must be a polymer of glucose.

  3. Use the nature of glycosidic linkage

    The question further states that XXX contains only β\betaβ-glycosidic linkages.

    Now examine the options:

    • Starch: polymer of α\alphaα-D-glucose; contains α\alphaα-linkages
    • Amylose: component of starch; has α(1→4)\alpha(1\to4)α(1→4) linkages
    • Amylopectin: has α(1→4)\alpha(1\to4)α(1→4) and α(1→6)\alpha(1\to6)α(1→6) linkages
    • Cellulose: polymer of β\betaβ-D-glucose; has only β(1→4)\beta(1\to4)β(1→4) glycosidic linkages
  4. Match all conditions

    Cellulose satisfies both conditions:

    • On hydrolysis, it gives glucose
    • It contains only β\betaβ-glycosidic linkages
  5. Evaluate options

    • A: starch →\to→ incorrect
    • B: cellulose →\to→ correct
    • C: amylose →\to→ incorrect
    • D: amylopectin →\to→ incorrect

Therefore, the compound XXX is:

Cellulose\boxed{\text{Cellulose}}Cellulose​

PreviousNext

More from Biomolecules

  • In alanylglycyl leucyl alanyl valine, the number of peptide linkages is ​.2022 · Numerical
  • During the denaturation of proteins, which of these structures will remain intact?2022 · MCQ
  • Glycosidic linkage between C1 of α-glucose and C2 of β-fructose is found in2022 · MCQ
  • How many of the given compounds will give a positive Biuret test ​ ? Glycine, Glycylalanine, Tripeptide, Biuret2022 · Numerical
  • Which one of the following is a reducing sugar?2022 · MCQ
  • Animal starch is the other name of2022 · MCQ
  • The number of oxygens present in a nucleotide formed from a base, that is present only in RNA is ​.2022 · Numerical
  • Which one of the following is a water soluble vitamin, that is not excreted easily?2022 · MCQ