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Biomolecules question

2020 · 5 Sep · Shift 2 · Q3
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Biomolecules question

2020 · 5 Sep · Shift 2 · Q3

JEE MainChemistryBiomoleculesNumerical+4 / −1
The number of chiral carbons present in sucrose is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 9

  1. Identify the components of sucrose

    Sucrose is a disaccharide made of:

    • α\alphaα-D-glucopyranose
    • β\betaβ-D-fructofuranose

    linked through a glycosidic bond between:

    • C1_11​ of glucose
    • C2_22​ of fructose
  2. Count chiral carbons in the glucose unit

    In glucopyranose, the chiral carbons are: C1,C2,C3,C4,C5C_1, C_2, C_3, C_4, C_5C1​,C2​,C3​,C4​,C5​

    So, glucose contributes: 5 chiral carbons5 \text{ chiral carbons}5 chiral carbons

  3. Count chiral carbons in the fructose unit

    In fructofuranose, the chiral carbons are: C2,C3,C4,C5C_2, C_3, C_4, C_5C2​,C3​,C4​,C5​

    So, fructose contributes: 4 chiral carbons4 \text{ chiral carbons}4 chiral carbons

  4. Effect of glycosidic bond formation

    The glycosidic bond forms between the two anomeric carbons, but these carbons remain stereogenic centers in the cyclic structure.

    Therefore, total chiral carbons in sucrose are: 5+4=95 + 4 = 95+4=9

  5. Final answer

    9\boxed{9}9​

  6. Comparison with stored correct answer

    Stored correct answer = 999

    Our derived answer also = 999

    Hence, the answer agrees with the stored correct answer.

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