- AGluconic acid can from cyclic (acteal/hemiacetal) structure
- BGluconic acid is a partial oxidation product of glucose
- CGluconic acid is obtained by oxidation of glucose with ()
- DGluconic acid is a dicarboxylic acid.
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Correct answer: B
-
Identify what gluconic acid is
Glucose is an aldohexose, so it contains:
- one aldehyde group at
- one primary alcohol group at
On mild oxidation of glucose, only the aldehyde group gets oxidized to a carboxylic acid.
Thus:
So gluconic acid is:
-
Check each option
Option A: "Gluconic acid can form cyclic (acetal/hemiacetal) structure"
For a hemiacetal/cyclic hemiacetal, a molecule needs an aldehyde or ketone group to react intramolecularly with an alcohol group.
In gluconic acid, the aldehyde group of glucose has already been oxidized to . Therefore, it cannot form a cyclic hemiacetal/acetal like glucose.
So, A is incorrect.
Option B: "Gluconic acid is a partial oxidation product of glucose"
This is true because only the aldehyde group is oxidized, while the terminal group remains unchanged.
Hence, gluconic acid is indeed a partial oxidation product of glucose.
So, B is correct.
Option C: "Gluconic acid is obtained by oxidation of glucose with "
Oxidation with nitric acid is a strong oxidation. It oxidizes both:
- the aldehyde group at to
- the primary alcohol group at to
This gives saccharic acid (glucaric acid), not gluconic acid.
So, C is incorrect.
Option D: "Gluconic acid is a dicarboxylic acid"
Gluconic acid contains only one carboxylic acid group. Therefore, it is not a dicarboxylic acid.
So, D is incorrect.
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Final answer
The only correct statement is:
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