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Biomolecules question

2020 · 7 Jan · Shift 2 · Q6
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Biomolecules question

2020 · 7 Jan · Shift 2 · Q6

JEE MainChemistryBiomoleculesMCQ+4 / −1
Which of the following statements is correct ?
  1. A
    Gluconic acid can from cyclic (acteal/hemiacetal) structure
  2. B
    Gluconic acid is a partial oxidation product of glucose
  3. C
    Gluconic acid is obtained by oxidation of glucose with (HNO3HNO_3HNO3​)
  4. D
    Gluconic acid is a dicarboxylic acid.
View written solutionFree

Correct answer: B

  1. Identify what gluconic acid is

    Glucose is an aldohexose, so it contains:

    • one aldehyde group at C1C_1C1​
    • one primary alcohol group at C6C_6C6​

    On mild oxidation of glucose, only the aldehyde group gets oxidized to a carboxylic acid.

    Thus: Glucose→mild oxidationGluconic acid\text{Glucose} \xrightarrow[\text{mild oxidation}]{} \text{Gluconic acid}Glucosemild oxidation​Gluconic acid

    So gluconic acid is: HOCH2(CHOH)4COOH\text{HOCH}_2(\text{CHOH})_4\text{COOH}HOCH2​(CHOH)4​COOH

  2. Check each option

    Option A: "Gluconic acid can form cyclic (acetal/hemiacetal) structure"

    For a hemiacetal/cyclic hemiacetal, a molecule needs an aldehyde or ketone group to react intramolecularly with an alcohol group.

    In gluconic acid, the aldehyde group of glucose has already been oxidized to −COOH-COOH−COOH. Therefore, it cannot form a cyclic hemiacetal/acetal like glucose.

    So, A is incorrect.

    Option B: "Gluconic acid is a partial oxidation product of glucose"

    This is true because only the aldehyde group is oxidized, while the terminal −CH2OH-CH_2OH−CH2​OH group remains unchanged.

    Hence, gluconic acid is indeed a partial oxidation product of glucose.

    So, B is correct.

    Option C: "Gluconic acid is obtained by oxidation of glucose with HNO3HNO_3HNO3​"

    Oxidation with nitric acid is a strong oxidation. It oxidizes both:

    • the aldehyde group at C1C_1C1​ to −COOH-COOH−COOH
    • the primary alcohol group at C6C_6C6​ to −COOH-COOH−COOH

    This gives saccharic acid (glucaric acid), not gluconic acid.

    So, C is incorrect.

    Option D: "Gluconic acid is a dicarboxylic acid"

    Gluconic acid contains only one carboxylic acid group. Therefore, it is not a dicarboxylic acid.

    So, D is incorrect.

  3. Final answer

    The only correct statement is: B\boxed{\text{B}}B​

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