- AStatement I is true but Statement II is false
- BBoth Statement I and Statement II are true
- CBoth Statement I and Statement II are false
- DStatement I is false but Statement II is true
View written solutionFree
Correct answer: B
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Analyze Statement (II) first
We know the directing effects in electrophilic aromatic substitution:
- is an electron-donating group by hyperconjugation and inductive effect, so it is ortho/para-directing.
- is a strong electron-withdrawing group, so it is meta-directing.
Therefore, Statement (II) is true.
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Now analyze Statement (I)
The substrate is m-xylene, i.e. -dimethylbenzene.
Its structure has methyl groups at positions 1 and 3:
We now nitrate it using .
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Directing effects during nitration
Each group is ortho/para-directing.
For m-xylene, possible nitration positions are 2, 4, 5, and 6.
- Position 2: ortho to both methyl groups → sterically crowded
- Position 4: para to one methyl and ortho to the other
- Position 6: similar to position 2 by symmetry considerations
- Position 5: meta to one methyl and ortho/para relation less favored overall
The major nitration product is formed at position 4, giving 4-nitro-m-xylene (equivalently 2-nitro-1,3-dimethylbenzene depending on numbering convention).
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Oxidation step
Strong oxidation converts each benzylic group into .
So:
Hence, Statement (I) is also true.
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Conclusion
- Statement (I): True
- Statement (II): True
Therefore, the correct option is:
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Comparison with stored correct answer
Stored correct answer = B
Our derived answer = B
So, they agree.
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