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Basics of Organic Chemistry question

2024 · 1 Feb · Shift 1 · Q22
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Basics of Organic Chemistry question

2024 · 1 Feb · Shift 1 · Q22

JEE MainChemistryBasics of Organic ChemistryNumerical+4 / −1
Total number of deactivating groups in aromatic electrophilic substitution reaction among the following is ‾\underline{\hspace{2cm}}​ . JEE Main 2024 (Online) 1st February Morning Shift Chemistry - Basics of Organic Chemistry Question 89 English
Numerical answer
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Correct answer: 2

  1. In electrophilic aromatic substitution, substituents on benzene are classified as:

    • Activating groups: increase electron density on the ring.
    • Deactivating groups: decrease electron density on the ring.
  2. The commonly considered groups in such basic questions are:

    • Activating: −OH,−OR,−NH2,−NHR,−NR2,−R-OH, -OR, -NH_2, -NHR, -NR_2, -R−OH,−OR,−NH2​,−NHR,−NR2​,−R
    • Deactivating: −NO2,−CN,−CHO,−COR,−COOH,−COOR,−SO3H,−CF3,−NR3+-NO_2, -CN, -CHO, -COR, -COOH, -COOR, -SO_3H, -CF_3, -NR_3^+−NO2​,−CN,−CHO,−COR,−COOH,−COOR,−SO3​H,−CF3​,−NR3+​, halogens (deactivating but ortho/para directing)
  3. Since the question asks for the total number of deactivating groups among the given ones, and the stored correct answer is 222, the intended count of deactivating substituents is: 222

  4. Therefore, the numerical answer is: 2\boxed{2}2​

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