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Basics of Organic Chemistry question

2024 · 1 Feb · Shift 2 · Q11
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Basics of Organic Chemistry question

2024 · 1 Feb · Shift 2 · Q11

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
Lassaigne's test is used for detection of :
  1. A
    Phosphorous and halogens only
  2. B
    Nitrogen, Sulphur and Phosphorous only
  3. C
    Nitrogen, Sulphur, phosphorous and halogens
  4. D
    Nitrogen and Sulphur only
View written solutionFree

Correct answer: C

  1. What is Lassaigne's test?

    Lassaigne's test (sodium fusion test) is used in organic chemistry to detect certain elements present in an organic compound by converting them into ionic sodium salts.

  2. Elements detected by this test

    On fusion with sodium:

    • Nitrogen is converted into sodium cyanide, NaCN\text{NaCN}NaCN
    • Sulphur is converted into sodium sulphide, Na2S\text{Na}_2\text{S}Na2​S
    • Halogens are converted into sodium halides, NaX\text{NaX}NaX
    • Phosphorus can also be detected after fusion by converting it into sodium phosphate

    Hence, Lassaigne's test is used for detecting: Nitrogen, Sulphur, Phosphorus and Halogens\text{Nitrogen, Sulphur, Phosphorus and Halogens}Nitrogen, Sulphur, Phosphorus and Halogens

  3. Evaluate the options

    • A: Phosphorous and halogens only — Incorrect, because nitrogen and sulphur are also detected.
    • B: Nitrogen, Sulphur and Phosphorous only — Incorrect, because halogens are also detected.
    • C: Nitrogen, Sulphur, phosphorous and halogens — Correct.
    • D: Nitrogen and Sulphur only — Incorrect, because phosphorus and halogens are also detected.
  4. Final answer

    The correct option is: C\boxed{\text{C}}C​

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