
- A4-Hydroxyhept-6-en-1-yne
- BHept-1-en-6-yn-4-ol
- CHept-6-en-1-yn-4-ol
- D4-Hydroxyhept-1-en-6-yne
View written solutionFree
Correct answer: B
-
Identify the parent carbon chain
The compound has a longest chain of 7 carbons, so the parent name begins with hept-.
-
Identify the functional groups and multiple bonds
From the structure/options, the molecule contains:
- one alcohol group:
- one double bond:
- one triple bond:
Hence the suffix must include ol, en, and yn.
-
Choose the principal functional group
The alcohol group has highest priority among these, so numbering must give the lowest possible locant to .
In all options, the hydroxyl group is at carbon , so this condition is satisfied either way.
-
Resolve numbering using multiple bonds
Since the hydroxyl locant is tied, we next minimize the locants of the multiple bonds.
Compare the two possible numberings:
-
One direction gives:
- double bond at
- triple bond at
- alcohol at
So locants:
-
Opposite direction gives:
- double bond at
- triple bond at
- alcohol at
So locants:
For enyne systems, when there is a choice, the set with the lowest locant at the first point of difference is preferred. Thus is preferred over .
Therefore numbering should be:
- alkene at
- alkyne at
- alcohol at
-
-
Write the IUPAC name
The correct format is:
-
Check the options
- A: 4-Hydroxyhept-6-en-1-yne ❌ Older-style naming; also not preferred because alcohol should be suffix, not prefix.
- B: Hept-1-en-6-yn-4-ol ✅
- C: Hept-6-en-1-yn-4-ol ❌
- D: 4-Hydroxyhept-1-en-6-yne ❌
-
Comparison with stored correct answer
My derived answer is B, which matches the stored correct answer.
More from Basics of Organic Chemistry
- Which of the following is the correct IUPAC name of given organic compound (X)? Includes diagram2025 · MCQ
- The descending order of basicity of the following amines is : (D) (E) Choose the correct answer from the options given below : Includes diagram2025 · MCQ
- The number of optically active products obtained from the complete ozonolysis of the given compound is : Includes diagram2025 · MCQ
- Match the LIST-I with LIST-II Choose the correct answer from the options given below: Includes table2025 · MCQ
- What is the correct IUPAC name of the compound? Includes diagram2025 · MCQ
- The incorrect statements regarding geometrical isomerism are : (A) Propene shows geometrical isomerism. (B) Trans isomer has identical atoms/groups on the opposite sides of the double bond. (C) Cis-but-2-ene has higher dipole moment than…2025 · MCQ
- The IUPAC name of the following compound is : Includes diagram2025 · MCQ
- In Carius method for estimation of halogens, 180 mg of an organic compound produced 143.5 mg of AgCl . The percentage composition of chlorine in the compound is %. (Given : molar mass in …2025 · Numerical