JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
?- A3-Bromo-2-hydroxy-5-nitrobenzoic acid
- B2-Hydroxy-3-bromo-5-nitrobenzoic acid
- C3-Bromo-4-hydroxy-1-nitrobenzoic acid
- D5-Nitro-3-bromo-2-hydroxybenzoic acid
View written solutionFree
Correct answer: A
-
Identify the parent functional group
The compound is a substituted benzoic acid, since the principal functional group is the carboxylic acid group, .
Therefore, the parent name is:
-
Assign numbering on the benzene ring
In benzoic acid, the carbon attached to is taken as position .
Number the ring so that the substituents get the lowest possible set of locants.
From the given structure, the substituents are:
- at position
- at position
- at position
So the locants are:
-
Arrange substituents in alphabetical order
Prefixes must be written in alphabetical order:
- bromo
- hydroxy
- nitro
Hence the name becomes:
-
Check the options
- A: ✅ Correct
- B: ❌ Same locants, but substituents are not arranged alphabetically
- C: ❌ Incorrect numbering and parent naming
- D: ❌ Substituents not in alphabetical order
-
Final answer
The correct IUPAC name is:
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