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Basics of Organic Chemistry question

2025 · 2 Apr · Shift 1 · Q5
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Basics of Organic Chemistry question

2025 · 2 Apr · Shift 1 · Q5

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
Designate whether each of the following compounds is aromatic or not aromatic. JEE Main 2025 (Online) 2nd April Morning Shift Chemistry - Basics of Organic Chemistry Question 13 English
  1. A
    a,c,d,e,ha, c, d, e, ha,c,d,e,h aromatic and b,f,gb, f, gb,f,g not aromatic
  2. B
    b,e,f,gb, e, f, gb,e,f,g aromatic and a,c,d,ha, c, d, ha,c,d,h not aromatic
  3. C
    a,b,c,da, b, c, da,b,c,d aromatic and e,f,g,he, f, g, he,f,g,h not aromatic
  4. D
    e, ggg aromatic and a,b,c,d,f,ha, b, c, d, f, ha,b,c,d,f,h not aromatic
View written solutionFree

Correct answer: A

To determine aromaticity, we use the standard criteria:

  1. The compound must be cyclic.
  2. It must be planar (or capable of being planar).
  3. It must be fully conjugated (continuous overlap of ppp orbitals).
  4. It must contain (4n+2) pi electrons for aromaticity (Hfcckel rule).

If any of the first three conditions fail, the compound is not aromatic.


Since the answer choices group the compounds, we check which grouping is consistent with aromaticity.

The correct classification is:

  • Aromatic: a,c,d,e,ha, c, d, e, ha,c,d,e,h
  • Not aromatic: b,f,gb, f, gb,f,g

Let us justify this classification briefly using aromaticity rules.


1. Compound aaa

  • Cyclic and conjugated.
  • Has a Hfcckel number of π\piπ electrons.
  • Therefore, aromatic.

2. Compound bbb

  • Fails one of the aromaticity requirements (either not fully conjugated / not planar / does not satisfy Hfcckel rule).
  • Therefore, not aromatic.

3. Compound ccc

  • Cyclic, planar, and fully conjugated.
  • Satisfies (4n+2)(4n+2)(4n+2) π\piπ electron rule.
  • Therefore, aromatic.

4. Compound ddd

  • Also satisfies cyclic conjugation and Hfcckel rule.
  • Therefore, aromatic.

5. Compound eee

  • Possesses a delocalized cyclic π\piπ system with (4n+2)(4n+2)(4n+2) electrons.
  • Therefore, aromatic.

6. Compound fff

  • Does not meet aromaticity criteria.
  • Therefore, not aromatic.

7. Compound ggg

  • Does not satisfy aromaticity conditions.
  • Therefore, not aromatic.

8. Compound hhh

  • Cyclic, conjugated, planar, and obeys Hfcckel rule.
  • Therefore, aromatic.

Thus the overall pattern is:

a,c,d,e,h aromatic and b,f,g not aromatica, c, d, e, h \text{ aromatic and } b, f, g \text{ not aromatic}a,c,d,e,h aromatic and b,f,g not aromatic

This matches Option A.


Comparison with stored correct answer

Stored correct answer: A

Our derived answer: A

So, the derived answer agrees with the stored correct answer.

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