- AStatement I is false but Statement II is true
- BStatement I is true but Statement II is false
- CBoth Statement I and Statement II are false
- DBoth Statement I and Statement II are true
View written solutionFree
Correct answer: A
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Analyze Statement I: "Hyperconjugation is not a permanent effect."
Hyperconjugation is a delocalization effect involving overlap of a -bond (usually or ) with an adjacent empty -orbital or -system.
In standard organic chemistry classification, hyperconjugation is treated as a permanent electronic effect because it exists in the ground state of the molecule whenever the required structural arrangement is present.
Therefore, the statement "Hyperconjugation is not a permanent effect" is false.
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Analyze Statement II: "In general, greater the number of alkyl groups attached to a positively charged C atom, greater is the hyperconjugation interaction and stabilization of the cation."
For carbocations, alkyl groups provide adjacent bonds that can participate in hyperconjugation with the empty -orbital on the positively charged carbon.
Hence, more alkyl groups generally mean more hyperconjugative structures and greater stabilization:
So Statement II is true.
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Conclusion:
- Statement I = False
- Statement II = True
Therefore, the correct option is:
A: Statement I is false but Statement II is true.
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