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Basics of Organic Chemistry question

2025 · 3 Apr · Shift 2 · Q12
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Basics of Organic Chemistry question

2025 · 3 Apr · Shift 2 · Q12

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
Given below are two statements : Statement I : Hyperconjugation is not a permanent effect. Statement II : In general, greater the number of alkyl groups attached to a positively charged Catom, greater is the hyperconjugation interaction and stabilization of the cation. In the light of the above statements, choose the correct answer from the options given below
  1. A
    Statement I is false but Statement II is true
  2. B
    Statement I is true but Statement II is false
  3. C
    Both Statement I and Statement II are false
  4. D
    Both Statement I and Statement II are true
View written solutionFree

Correct answer: A

  1. Analyze Statement I: "Hyperconjugation is not a permanent effect."

    Hyperconjugation is a delocalization effect involving overlap of a σ\sigmaσ-bond (usually C–H\text{C–H}C–H or C–C\text{C–C}C–C) with an adjacent empty ppp-orbital or π\piπ-system.

    In standard organic chemistry classification, hyperconjugation is treated as a permanent electronic effect because it exists in the ground state of the molecule whenever the required structural arrangement is present.

    Therefore, the statement "Hyperconjugation is not a permanent effect" is false.

  2. Analyze Statement II: "In general, greater the number of alkyl groups attached to a positively charged C atom, greater is the hyperconjugation interaction and stabilization of the cation."

    For carbocations, alkyl groups provide adjacent C–H\text{C–H}C–H bonds that can participate in hyperconjugation with the empty ppp-orbital on the positively charged carbon.

    Hence, more alkyl groups generally mean more hyperconjugative structures and greater stabilization:

    3∘>2∘>1∘>methyl cation3^\circ > 2^\circ > 1^\circ > \text{methyl cation}3∘>2∘>1∘>methyl cation

    So Statement II is true.

  3. Conclusion:

    • Statement I = False
    • Statement II = True

    Therefore, the correct option is:

    A: Statement I is false but Statement II is true.

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