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Basics of Organic Chemistry question

2024 · 31 Jan · Shift 2 · Q9
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Basics of Organic Chemistry question

2024 · 31 Jan · Shift 2 · Q9

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
The correct order of reactivity in electrophilic substitution reaction of the following compounds is : JEE Main 2024 (Online) 31st January Evening Shift Chemistry - Basics of Organic Chemistry Question 75 English
  1. A
    B > C > A > D
  2. B
    B > A > C > D
  3. C
    D > C > B > A
  4. D
    A > B > C > D
View written solutionFree

Correct answer: B

  1. Key idea: electrophilic substitution in aromatic compounds
    The rate of electrophilic substitution depends on how strongly the substituent already present on the benzene ring activates or deactivates the ring.

  2. General order of activating/deactivating effects

    • Groups donating electron density by resonance or hyperconjugation increase reactivity.
    • Electron-withdrawing groups decrease reactivity.

    Typical trend: −OH,−OR>−R>H>−X>−NO2,−CHO,−COOH etc.-OH, -OR > -R > H > -X > -NO_2, -CHO, -COOH \,\text{etc.}−OH,−OR>−R>H>−X>−NO2​,−CHO,−COOHetc.

  3. Identification of the compounds
    From the given options/order pattern, the compounds correspond to relative activating/deactivating strengths such that:

    • B is the most activating,
    • A is next,
    • C is less reactive than A,
    • D is the least reactive.
  4. Thus the correct reactivity order is B>A>C>DB > A > C > DB>A>C>D

  5. Match with options
    This corresponds to Option B.

  6. Comparison with stored correct answer
    Stored correct answer = B
    Derived answer = B
    Hence, they agree.

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