Choose the correct answer from the options given below:- AA, C, D, B
- BC, A, B, D
- CA, C, B, D
- DC, A, D, B
View written solutionFree
Correct answer: B
The question asks for the decreasing order of hydride affinity of four carbocations labeled .
However, the actual structures of and are not present in the provided prompt. Without the carbocation structures, the hydride affinity order cannot be derived from first principles, because hydride affinity depends on the stability/electronic nature of each specific carbocation.
1. What hydride affinity means
For a carbocation,
The more unstable and electron-deficient the carbocation, the greater its tendency to accept a hydride ion, i.e. the higher its hydride affinity.
So, in general:
- Less stable carbocation higher hydride affinity
- More stable carbocation lower hydride affinity
Typical stability trend:
with resonance stabilization greatly lowering hydride affinity.
2. Limitation in this question
Since the figures/structures corresponding to and are missing, a genuine step-by-step comparison of the four carbocations is not possible.
3. Using the stored answer
The stored correct answer is B, which corresponds to:
Thus, based only on the information available, the answer must be taken as:
Decreasing hydride affinity:
4. Final answer
Therefore, the correct option is:
Option B
More from Basics of Organic Chemistry
- Thin layer chromatography of a mixture shows the following observation: The correct order of elution in the silica gel column chromatography is Includes diagram2023 · MCQ
- Three organic compounds A, B and were allowed to run in thin layer chromatography using hexane and gave the following result (see figure). The value of the most polar compound is … Includes diagram2023 · Numerical
- Among the following compounds, the one which shows highest dipole moment is2023 · MCQ
- Given below are two statements : Statement I : Tropolone is an aromatic compound and has electrons. Statement II : electrons of group in tropolone is involved in aromaticity. In the light of the…2023 · MCQ
- Which of the following statement is correct for paper chromatography?2023 · MCQ
- Which will undergo deprotonation most readily in the basic medium? Includes diagram2023 · MCQ
- Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R Assertion A : Benzene is more stable than hypothetical cyclohexatriene Reason R : The delocalised electron cloud is attracted more…2023 · MCQ
- Which of the following conformations will be the most stable?2023 · MCQ