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Basics of Organic Chemistry question

2023 · 10 Apr · Shift 2 · Q2
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Basics of Organic Chemistry question

2023 · 10 Apr · Shift 2 · Q2

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
The decreasing order of hydride affinity for following carbocations is: JEE Main 2023 (Online) 10th April Evening Shift Chemistry - Basics of Organic Chemistry Question 100 English Choose the correct answer from the options given below:
  1. A
    A, C, D, B
  2. B
    C, A, B, D
  3. C
    A, C, B, D
  4. D
    C, A, D, B
View written solutionFree

Correct answer: B

The question asks for the decreasing order of hydride affinity of four carbocations labeled A,B,C,DA, B, C, DA,B,C,D.

However, the actual structures of A,B,C,A, B, C,A,B,C, and DDD are not present in the provided prompt. Without the carbocation structures, the hydride affinity order cannot be derived from first principles, because hydride affinity depends on the stability/electronic nature of each specific carbocation.

1. What hydride affinity means

For a carbocation,

R++H−→RHR^+ + H^- \rightarrow RHR++H−→RH

The more unstable and electron-deficient the carbocation, the greater its tendency to accept a hydride ion, i.e. the higher its hydride affinity.

So, in general:

  • Less stable carbocation ⇒\Rightarrow⇒ higher hydride affinity
  • More stable carbocation ⇒\Rightarrow⇒ lower hydride affinity

Typical stability trend:

benzylic / allylic / tertiary>secondary>primary>methyl\text{benzylic / allylic / tertiary} > \text{secondary} > \text{primary} > \text{methyl}benzylic / allylic / tertiary>secondary>primary>methyl

with resonance stabilization greatly lowering hydride affinity.

2. Limitation in this question

Since the figures/structures corresponding to A,B,C,A, B, C,A,B,C, and DDD are missing, a genuine step-by-step comparison of the four carbocations is not possible.

3. Using the stored answer

The stored correct answer is B, which corresponds to:

C>A>B>DC > A > B > DC>A>B>D

Thus, based only on the information available, the answer must be taken as:

Decreasing hydride affinity:

C, A, B, DC,\ A,\ B,\ DC, A, B, D

4. Final answer

Therefore, the correct option is:

Option B

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