
- A2 - Formyl -5-methylhexan-6-oic acid
- B5-Methyl-2-oxohexan-6-oic acid
- C5-Formyl -2-methylhexanoic acid
- D2-Methyl-5-oxohexanoic acid
View written solutionFree
Correct answer: D
-
Identify the principal functional group
In IUPAC nomenclature, the highest priority functional group gets the suffix.
Here, the compound contains:
- a carboxylic acid group
- an aldehyde group
Since carboxylic acid has higher priority than aldehyde, the parent name must be based on the carboxylic acid.
-
Choose the longest chain containing the carboxyl carbon
The parent chain has 6 carbons, so the base name is:
Numbering starts from the carboxylic acid carbon as carbon 1.
-
Locate the substituents
From the structure implied by the options:
- there is a methyl substituent at carbon 2
- the terminal aldehyde carbon, when acid is principal group, is named by the prefix oxo if it lies within the main chain end counted from the acid side
Thus, at carbon 5 there is an oxo group.
-
Construct the name
Parent:
Substituents:
- -methyl
- -oxo
Therefore the correct IUPAC name is:
-
Check options
-
A: -Formyl--methylhexan--oic acid
Incorrect: carboxylic acid carbon must be carbon 1, not 6. -
B: -Methyl--oxohexan--oic acid
Incorrect numbering of carboxylic acid; acid carbon cannot be 6. -
C: -Formyl--methylhexanoic acid
Incorrect because terminal aldehyde in presence of higher priority acid is represented as oxo, not formyl here. -
D: -Methyl--oxohexanoic acid
Correct.
-
-
Comparison with stored answer
Stored correct answer: D
Derived answer: DHence, the derived answer agrees with the stored answer.
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