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Basics of Organic Chemistry question

2024 · 29 Jan · Shift 1 · Q15
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Basics of Organic Chemistry question

2024 · 29 Jan · Shift 1 · Q15

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
The interaction between π\piπ bond and lone pair of electrons present on an adjacent atom is responsible for
  1. A
    Resonance effect
  2. B
    Electromeric effect
  3. C
    Hyperconjugation
  4. D
    Inductive effect
View written solutionFree

Correct answer: A

  1. Identify the interaction described

    The question says:

    interaction between a π\piπ bond and a lone pair of electrons present on an adjacent atom

    This is the classic condition for resonance (also called the mesomeric effect), where electron density is delocalized through overlap of adjacent ppp orbitals.

  2. Recall the definitions of the given effects

    • Resonance effect: Delocalization of electrons due to interaction of

      • π\piπ bond with π\piπ bond, or
      • π\piπ bond with lone pair, or
      • lone pair with positive charge/vacant orbital.
    • Electromeric effect: Temporary complete transfer of a π\piπ electron pair to one atom in presence of an attacking reagent.

    • Hyperconjugation: Delocalization involving σ\sigmaσ bonds (usually C−HC-HC−H) adjacent to a multiple bond or carbocation.

    • Inductive effect: Permanent polarization of σ\sigmaσ bonds due to electronegativity differences.

  3. Match the description

    Since the question specifically mentions interaction between a π\piπ bond and a lone pair on an adjacent atom, this corresponds to resonance effect.

  4. Check options

    • A: Resonance effect →\rightarrow→ Correct
    • B: Electromeric effect →\rightarrow→ Incorrect
    • C: Hyperconjugation →\rightarrow→ Incorrect
    • D: Inductive effect →\rightarrow→ Incorrect
  5. Final answer

    The correct option is A.

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