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Basics of Organic Chemistry question

2024 · 30 Jan · Shift 2 · Q4
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Basics of Organic Chemistry question

2024 · 30 Jan · Shift 2 · Q4

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
IUPAC name of following compound is : JEE Main 2024 (Online) 30th January Evening Shift Chemistry - Basics of Organic Chemistry Question 65 English
  1. A
    2-Aminobutanenitrile
  2. B
    3-Aminopropanenitrile
  3. C
    2-Aminopentanenitrile
  4. D
    3-Aminobutanenitrile
View written solutionFree

Correct answer: D

  1. Identify the principal functional group

    The suffix nitrile has higher priority than the amino group, so the parent chain must include the carbon of the −C≡N-C\equiv N−C≡N group.

  2. Count the carbon atoms in the parent chain

    For nitriles, the carbon of the cyano group is counted as carbon 1.

    The structure corresponds to: CH3−CH(NH2)−CH2−C≡N\mathrm{CH_3-CH(NH_2)-CH_2-C\equiv N}CH3​−CH(NH2​)−CH2​−C≡N

    Counting from the nitrile carbon:

    • Carbon 1: nitrile carbon (−C≡N)(-C\equiv N)(−C≡N)
    • Carbon 2: CH2CH_2CH2​
    • Carbon 3: CH(NH2)CH(NH_2)CH(NH2​)
    • Carbon 4: CH3CH_3CH3​

    So the parent chain has 4 carbons ⇒\Rightarrow⇒ butanenitrile.

  3. Locate the amino substituent

    The −NH2-NH_2−NH2​ group is on carbon 3.

  4. Write the IUPAC name

    Therefore, the IUPAC name is: 3-Aminobutanenitrile\boxed{\text{3-Aminobutanenitrile}}3-Aminobutanenitrile​

  5. Check options

    • A: 2-Aminobutanenitrile →\rightarrow→ wrong position of amino group
    • B: 3-Aminopropanenitrile →\rightarrow→ wrong chain length
    • C: 2-Aminopentanenitrile →\rightarrow→ wrong chain length
    • D: 3-Aminobutanenitrile →\rightarrow→ correct

Hence, the correct option is D.

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