JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
The ascending acidity order of the following H atoms is 

- AA < B < D < C
- BA < B < C < D
- CD < C < B < A
- DC < D < B < A
View written solutionFree
Correct answer: D
To determine the ascending acidity order of the labeled hydrogen atoms, we compare the stability of the conjugate bases formed after removal of each H.
1. Principle used
A hydrogen is more acidic if the anion formed after its removal is more stable.
In organic molecules, acidity increases when the negative charge in the conjugate base is stabilized by:
- Resonance
- Electron-withdrawing groups
- Greater s-character of the carbon bearing the charge
- Aromatic stabilization, if applicable
2. Comparison of the given hydrogens
From the structures, the labeled hydrogens correspond to different types of carbon environments.
- A: least stabilized carbanion after deprotonation
- B: slightly more stabilized than A
- D: more acidic than B
- C: most stabilized conjugate base, hence most acidic
Thus, the acidity increases in the order:
3. Match with options
The option corresponding to
is:
Option A
4. Comparison with stored correct answer
- Derived answer: A
- Stored correct answer: D
These do not match.
Hence, I disagree with the stored answer.
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