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Basics of Organic Chemistry question

2024 · 5 Apr · Shift 2 · Q23
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  5. /2024 · 5 Apr · Shift 2 · Q23

Basics of Organic Chemistry question

2024 · 5 Apr · Shift 2 · Q23

JEE MainChemistryBasics of Organic ChemistryNumerical+4 / −1
Using the given figure, the ratio of Rf\mathrm{R}_fRf​ values of sample A\mathrm{A}A and sample C\mathrm{C}C is x×10−2x \times 10^{-2}x×10−2. Value of xxx is ‾\underline{\hspace{2cm}}​. JEE Main 2024 (Online) 5th April Evening Shift Chemistry - Basics of Organic Chemistry Question 39 English
Numerical answer
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Correct answer: 50

  1. The retention factor in chromatography is defined as Rf=distance travelled by solute spotdistance travelled by solvent front.R_f = \frac{\text{distance travelled by solute spot}}{\text{distance travelled by solvent front}}.Rf​=distance travelled by solvent frontdistance travelled by solute spot​.

  2. Since samples AAA and CCC are on the same chromatogram, the solvent front distance is the same for both. Therefore, Rf(A)Rf(C)=distance travelled by Adistance travelled by C.\frac{R_f(A)}{R_f(C)} = \frac{\text{distance travelled by }A}{\text{distance travelled by }C}.Rf​(C)Rf​(A)​=distance travelled by Cdistance travelled by A​.

  3. From the given figure, the spot of sample AAA has travelled half the distance travelled by sample CCC. Hence, Rf(A)Rf(C)=12=0.5.\frac{R_f(A)}{R_f(C)} = \frac{1}{2} = 0.5.Rf​(C)Rf​(A)​=21​=0.5.

  4. The question states that this ratio is x×10−2x \times 10^{-2}x×10−2. So, x×10−2=0.5x \times 10^{-2} = 0.5x×10−2=0.5 x=0.5×102=50.x = 0.5 \times 10^2 = 50.x=0.5×102=50.

  5. Therefore, the required value is 50.\boxed{50}.50​.

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