- Acis-2-butene and trans-2-butene are not interconvertible at room temperature.
- Btrans-2-butene is more stable than cis-2-butene.
- Ccis-2-butene has less dipole moment than trans-2-butene.
- Dcis-2-butene and trans-2-butene are stereoisomers.
View written solutionFree
Correct answer: C
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Identify the geometrical isomers of -butene
Structure of -butene is:
Since each carbon of the double bond has two different groups attached, it shows geometrical isomerism:
- cis-2-butene: both groups on the same side
- trans-2-butene: both groups on opposite sides
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Check each statement
Option A:
"cis-2-butene and trans-2-butene are not interconvertible at room temperature."
Interconversion of cis and trans forms would require rotation about the double bond, but rotation is restricted because of the bond.
Therefore, under normal conditions at room temperature, they are not interconvertible.
So, A is correct.
Option B:
"trans-2-butene is more stable than cis-2-butene."
In trans-2-butene, the two bulky groups are on opposite sides, so steric repulsion is less.
Hence, trans-2-butene is more stable than cis-2-butene.
So, B is correct.
Option C:
"cis-2-butene has less dipole moment than trans-2-butene."
In cis-2-butene, the bond dipoles do not cancel completely, so it has a non-zero dipole moment.
In trans-2-butene, due to symmetry, bond dipoles largely cancel out, so its dipole moment is very small (approximately zero).
Therefore:
The statement says cis has less dipole moment than trans, which is wrong.
So, C is incorrect.
Option D:
"cis-2-butene and trans-2-butene are stereoisomers."
Geometrical isomers are a type of stereoisomers because they differ in spatial arrangement of atoms.
So, D is correct.
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Conclusion
The incorrect statement is:
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