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Basics of Organic Chemistry question

2024 · 5 Apr · Shift 1 · Q1
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  5. /2024 · 5 Apr · Shift 1 · Q1

Basics of Organic Chemistry question

2024 · 5 Apr · Shift 1 · Q1

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : Cis form of alkene is found to be more polar than the trans form. Reason (R) : Dipole moment of trans isomer of 2-butene is zero. In the light of the above statements, choose the correct answer from the options given below :
  1. A
    (A) is true but (R) is false
  2. B
    (A) is false but (R) is true
  3. C
    Both (A)(\mathbf{A})(A) and (R)(\mathbf{R})(R) are true and (R)(\mathbf{R})(R) is the correct explanation of (A)(\mathbf{A})(A)
  4. D
    Both (A)(\mathbf{A})(A) and (R)(\mathbf{R})(R) are true but (R)(\mathbf{R})(R) is NOT the correct explanation of (A)(\mathbf{A})(A)
View written solutionFree

Correct answer: C

  1. Understand the assertion

    Assertion (A): Cis form of alkene is found to be more polar than the trans form.

    This is generally true for disubstituted alkenes like 222-butene.

    • In the cis isomer, the bond dipoles are on the same side, so they add up.
    • In the trans isomer, the bond dipoles are in opposite directions, so they tend to cancel.

    Therefore, the cis isomer is more polar than the trans isomer.

  2. Understand the reason

    Reason (R): Dipole moment of trans isomer of 2-butene is zero.

    Consider trans-2-butene:

    CH3−CH=CH−CH3\mathrm{CH_3-CH=CH-CH_3}CH3​−CH=CH−CH3​

    In the trans form, the two CH3\mathrm{CH_3}CH3​ groups lie on opposite sides of the double bond. Because of symmetry, the individual bond dipole moments cancel out.

    Hence,

    μ(trans-2-butene)=0\mu(\text{trans-2-butene}) = 0μ(trans-2-butene)=0

    So, the reason is also true.

  3. Check whether the reason explains the assertion

    Since the trans isomer has zero dipole moment due to cancellation, while the cis isomer has a non-zero dipole moment due to partial addition of dipoles, this directly explains why the cis form is more polar than the trans form.

    Therefore, (R) is the correct explanation of (A).

  4. Evaluate the options

    • A: (A) true, (R) false →\rightarrow→ Incorrect
    • B: (A) false, (R) true →\rightarrow→ Incorrect
    • C: Both true and (R) correctly explains (A) →\rightarrow→ Correct
    • D: Both true but (R) not correct explanation →\rightarrow→ Incorrect
  5. Final answer

    The correct option is:

    C\boxed{\text{C}}C​

  6. Comparison with stored answer

    Stored correct answer = C

    My derived answer = C

    So, they agree.

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