JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R Assertion A : Benzene is more stable than hypothetical cyclohexatriene Reason R : The delocalised electron cloud is attracted more strongly by nuclei of carbon atoms. In the light of the above statements, choose the correct answer from the options given below:
- AA is true but R is false
- BBoth A and R are correct and R is the correct explanation of A
- CBoth A and R are correct but R is NOT the correct explanation of A
- DA is false but R is true
View written solutionFree
Correct answer: B
-
Understand Assertion A
Assertion: Benzene is more stable than hypothetical cyclohexatriene.
This is true.
- If benzene were just a simple cyclohexatriene with three isolated double bonds, it should behave like a normal polyene.
- But benzene shows extra stability due to resonance/aromaticity.
- Its six electrons are delocalised over the entire ring.
- This delocalisation lowers the overall energy of the molecule, making benzene more stable than a hypothetical localized structure of cyclohexatriene.
-
Understand Reason R
Reason: The delocalised electron cloud is attracted more strongly by nuclei of carbon atoms.
This is also true.
- In benzene, the electrons are spread over all six carbon atoms.
- Because of delocalisation, the electron cloud is distributed symmetrically around the ring.
- This delocalised electron cloud experiences effective attraction from all the carbon nuclei, leading to stabilization.
-
Check whether R explains A
Yes, it does.
- Benzene’s greater stability arises from delocalisation of electrons.
- The delocalised electron cloud is stabilized by attraction to the carbon nuclei over the whole ring.
- Therefore, Reason R correctly explains why benzene is more stable than hypothetical cyclohexatriene.
-
Evaluate options
- A: A is true but R is false Incorrect
- B: Both A and R are correct and R is the correct explanation of A Correct
- C: Both A and R are correct but R is NOT the correct explanation of A Incorrect
- D: A is false but R is true Incorrect
Final Answer
Option B is correct.
More from Basics of Organic Chemistry
- Which of the following conformations will be the most stable?2023 · MCQ
- The correct order in aqueous medium of basic strength in case of methyl substituted amines is :2023 · MCQ
- Following chromatogram was developed by adsorption of compound 'A' on a 6 cm TLC glass plate. Retardation factor of the compound 'A' is . Includes diagram2023 · Numerical
- Match List I with List II: Includes table2023 · MCQ
- Match items of column I and II Correct match is Includes table Includes diagram2023 · MCQ
- Number of electrophilic centres in the given compound is . Includes diagram2022 · Numerical
- Which of the following is an example of conjugated diketone?2022 · MCQ
- Arrange the following carbocations in decreasing order of stability. Includes diagram2022 · MCQ