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Basics of Organic Chemistry question

2023 · 24 Jan · Shift 2 · Q4
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Basics of Organic Chemistry question

2023 · 24 Jan · Shift 2 · Q4

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R Assertion A : Benzene is more stable than hypothetical cyclohexatriene Reason R : The delocalised π\piπ electron cloud is attracted more strongly by nuclei of carbon atoms. In the light of the above statements, choose the correct answer from the options given below:
  1. A
    A is true but R is false
  2. B
    Both A and R are correct and R is the correct explanation of A
  3. C
    Both A and R are correct but R is NOT the correct explanation of A
  4. D
    A is false but R is true
View written solutionFree

Correct answer: B

  1. Understand Assertion A

    Assertion: Benzene is more stable than hypothetical cyclohexatriene.

    This is true.

    • If benzene were just a simple cyclohexatriene with three isolated double bonds, it should behave like a normal polyene.
    • But benzene shows extra stability due to resonance/aromaticity.
    • Its six π\piπ electrons are delocalised over the entire ring.
    • This delocalisation lowers the overall energy of the molecule, making benzene more stable than a hypothetical localized structure of cyclohexatriene.
  2. Understand Reason R

    Reason: The delocalised π\piπ electron cloud is attracted more strongly by nuclei of carbon atoms.

    This is also true.

    • In benzene, the π\piπ electrons are spread over all six carbon atoms.
    • Because of delocalisation, the electron cloud is distributed symmetrically around the ring.
    • This delocalised electron cloud experiences effective attraction from all the carbon nuclei, leading to stabilization.
  3. Check whether R explains A

    Yes, it does.

    • Benzene’s greater stability arises from delocalisation of π\piπ electrons.
    • The delocalised electron cloud is stabilized by attraction to the carbon nuclei over the whole ring.
    • Therefore, Reason R correctly explains why benzene is more stable than hypothetical cyclohexatriene.
  4. Evaluate options

    • A: A is true but R is false →\rightarrow→ Incorrect
    • B: Both A and R are correct and R is the correct explanation of A →\rightarrow→ Correct
    • C: Both A and R are correct but R is NOT the correct explanation of A →\rightarrow→ Incorrect
    • D: A is false but R is true →\rightarrow→ Incorrect

Final Answer

Option B is correct.

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