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Basics of Organic Chemistry question

2020 · 7 Jan · Shift 1 · Q19
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Basics of Organic Chemistry question

2020 · 7 Jan · Shift 1 · Q19

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
The increasing order to Pkb for the following compounds will be : JEE Main 2020 (Online) 7th January Morning Slot Chemistry - Basics of Organic Chemistry Question 192 English
  1. A
    (A) < (B) < (C)
  2. B
    (C) < (A) < (B)
  3. C
    (B) < (A) < (C)
  4. D
    (B) < (C) < (A)
View written solutionFree

Correct answer: C

The question asks for the increasing order of pKbpK_bpKb​ for three compounds (A)(A)(A), (B)(B)(B) and (C)(C)(C).

However, the actual structures of compounds AAA, BBB, and CCC are not visible/provided in the prompt. Without the structures, the basic strength cannot be compared, because pKbpK_bpKb​ depends on factors such as:

  1. Inductive effect
  2. Resonance effect
  3. Hybridisation of the atom bearing the lone pair
  4. Steric hindrance
  5. Solvation effects

Since the compounds themselves are missing, a definite chemical comparison cannot be derived from first principles.

What can still be concluded

For bases:

  • stronger base ⇒\Rightarrow⇒ smaller Kb−1K_b^{-1}Kb−1​ effect? More precisely,
  • stronger base ⇒\Rightarrow⇒ larger KbK_bKb​
  • hence stronger base ⇒\Rightarrow⇒ smaller pKbpK_bpKb​

So “increasing order of pKbpK_bpKb​” means:

strongest base<intermediate base<weakest base\text{strongest base} < \text{intermediate base} < \text{weakest base}strongest base<intermediate base<weakest base

in terms of pKbpK_bpKb​ values.

The stored correct answer is Option C:

(B)<(A)<(C)(B) < (A) < (C)(B)<(A)<(C)

Thus, according to the stored key, the basic strength order would be:

B>A>CB > A > CB>A>C

Limitation

Because the structures are absent, I cannot independently verify whether this order is chemically correct.

Therefore, I can only report that the stored answer is Option C, but this cannot be rigorously solved from the information shown.

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