JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
In the following compounds, the decreasing order of basic strength will be :
- A> >
- B> >
- C( > > )
- D> >
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Correct answer: C
- Identify the compounds
We need the decreasing order of basic strength among:
- (ammonia)
- (ethylamine, a primary amine)
- (diethylamine, a secondary amine)
- Recall the factor affecting basic strength
A base is stronger if the lone pair on nitrogen is more easily available for donation.
Alkyl groups like show a effect (electron-donating inductive effect), which increases electron density on nitrogen and makes the amine more basic than ammonia.
So, compared to :
- is more basic than
- is generally more basic than in aqueous medium among these choices
- Compare the three compounds
- has no alkyl group, so least electron donation.
- has one ethyl group, so nitrogen gets more electron density.
- has two ethyl groups, so even greater effect, making the lone pair most available.
Hence,
- Match with the options
Option C states:
which matches our result.
- Final answer
The decreasing order of basic strength is:
So, the correct option is C.
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