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Basics of Organic Chemistry question

2002 · Shift 0 · Q10
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Basics of Organic Chemistry question

2002 · Shift 0 · Q10

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
A similarity between optical and geometrical isomerism is that
  1. A
    each forms equal number of isomers for a given compound
  2. B
    if in a compound one is present then so is the other
  3. C
    both are included in stereoisomerism
  4. D
    they have no similarity
View written solutionFree

Correct answer: C

  1. Recall the definitions

    • Optical isomerism arises due to chirality. The isomers are non-superimposable mirror images of each other.
    • Geometrical isomerism arises due to restricted rotation (typically around a double bond or in cyclic compounds), giving cis-trans / E-Z forms.
  2. Identify the common feature

    Both optical and geometrical isomerism involve compounds having the same molecular formula and same connectivity of atoms, but differing in the spatial arrangement of atoms.

    Such isomerism is called stereoisomerism.

  3. Evaluate each option

    Option A: "each forms equal number of isomers for a given compound"

    • This is not generally true.
    • Optical isomerism may give 2 enantiomers, sometimes more in molecules with multiple chiral centers.
    • Geometrical isomerism may give 2 isomers in simple cases, but not always equal in all compounds.
    • So, A is false.

    Option B: "if in a compound one is present then so is the other"

    • A compound may show optical isomerism without geometrical isomerism, and vice versa.
    • Example: lactic acid shows optical isomerism but not geometrical isomerism.
    • 2-butene shows geometrical isomerism but not optical isomerism.
    • So, B is false.

    Option C: "both are included in stereoisomerism"

    • This is exactly correct.
    • Both optical and geometrical isomerism are types of stereoisomerism.
    • So, C is true.

    Option D: "they have no similarity"

    • False, because both belong to stereoisomerism.
  4. Conclusion

    The correct answer is: C\boxed{\text{C}}C​

  5. Comparison with stored correct answer

    Stored correct answer = C

    My derived answer = C

    Hence, they agree.

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