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Aldehydes Ketones and Carboxylic Acids question

2024 · 5 Apr · Shift 2 · Q10
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  5. /2024 · 5 Apr · Shift 2 · Q10

Aldehydes Ketones and Carboxylic Acids question

2024 · 5 Apr · Shift 2 · Q10

JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
Consider the given chemical reaction : JEE Main 2024 (Online) 5th April Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 31 English Product "A" is :
  1. A
    picric acid
  2. B
    oxalic acid
  3. C
    adipic acid
  4. D
    acetic acid
View written solutionFree

Correct answer: C

The question text says: "Consider the given chemical reaction: Product A is", but the actual reaction scheme/image is missing from the prompt. So the exact reaction cannot be read directly.

However, we can still infer the most likely answer from the given options and the chapter/topic:

  • Topic: Aldehydes, ketones and carboxylic acids
  • Options: picric acid, oxalic acid, adipic acid, acetic acid
  • Stored answer: C = adipic acid

Now, let us identify the common reaction in this chapter that gives adipic acid.


1. Common reaction leading to adipic acid

A very standard organic chemistry reaction is the strong oxidation of cyclohexanone / cyclohexanol (or related six-membered cyclic compounds) with oxidizing agents such as hot HNO3\mathrm{HNO_3}HNO3​, producing:

HOOC−(CH2)4−COOH\mathrm{HOOC-(CH_2)_4-COOH}HOOC−(CH2​)4​−COOH

This compound is adipic acid.

Its structure is:

Hexanedioic acid=HOOC−CH2−CH2−CH2−CH2−COOH\mathrm{Hexanedioic\ acid = HOOC-CH_2-CH_2-CH_2-CH_2-COOH}Hexanedioic acid=HOOC−CH2​−CH2​−CH2​−CH2​−COOH

So if the missing reaction involves oxidation of a cyclohexane ring ketone/alcohol, the product would indeed be adipic acid.


2. Checking the options

Option A: Picric acid

Picric acid is:

2,4,6−trinitrophenol\mathrm{2,4,6-trinitrophenol}2,4,6−trinitrophenol

This is formed by nitration of phenol-type aromatic systems, not by usual aldehyde/ketone oxidation in this chapter.

Option B: Oxalic acid

Oxalic acid is:

HOOC−COOH\mathrm{HOOC-COOH}HOOC−COOH

This is a two-carbon dicarboxylic acid, usually obtained by much deeper oxidative cleavage, not the common product from cyclohexanone oxidation.

Option C: Adipic acid

Adipic acid is:

HOOC−(CH2)4−COOH\mathrm{HOOC-(CH_2)_4-COOH}HOOC−(CH2​)4​−COOH

This is the well-known oxidation product of cyclohexanone/cyclohexanol.

Option D: Acetic acid

Acetic acid is:

CH3COOH\mathrm{CH_3COOH}CH3​COOH

This is also not the typical product in the standard reaction likely intended here.


3. Derived answer

Thus, the most plausible product AAA is:

Adipic acid\boxed{\text{Adipic acid}}Adipic acid​

So the correct option is:

C\boxed{\text{C}}C​


4. Comparison with stored correct answer

Stored correct answer = C

Our derived answer = C

So they agree.

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