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Alcohols Phenols and Ethers question

2022 · 29 Jul · Shift 1 · Q15
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Alcohols Phenols and Ethers question

2022 · 29 Jul · Shift 1 · Q15

JEE MainChemistryAlcohols Phenols and EthersMCQ+4 / −1
A compound 'X' is acidic and it is soluble in NaOHNaOHNaOH solution, but insoluble in NaHCO3NaHCO_3NaHCO3​ solution. Compound 'X' also gives violet colour with neutral FeCl3FeCl_3FeCl3​ solution. The compound 'X' is :
  1. A
    JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 63 English Option 1
  2. B
    JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 63 English Option 2
  3. C
    JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 63 English Option 3
  4. D
    JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 63 English Option 4
View written solutionFree

Correct answer: B

  1. Interpret the given tests

    We are told that compound XXX:

    • is acidic,
    • is soluble in NaOHNaOHNaOH,
    • is insoluble in NaHCO3NaHCO_3NaHCO3​,
    • gives violet colour with neutral FeCl3FeCl_3FeCl3​.
  2. Use acidity behavior

    • Compounds soluble in NaOHNaOHNaOH are generally acidic enough to form their sodium salts.
    • If a compound is insoluble in NaHCO3NaHCO_3NaHCO3​, then it is not acidic enough to react with sodium bicarbonate.

    This helps distinguish:

    • Carboxylic acids: react with both NaOHNaOHNaOH and NaHCO3NaHCO_3NaHCO3​.
    • Phenols: react with NaOHNaOHNaOH but do not react with NaHCO3NaHCO_3NaHCO3​ because they are weaker acids than carbonic acid.

    So, XXX is most likely a phenol.

  3. Use the FeCl3FeCl_3FeCl3​ test

    Neutral FeCl3FeCl_3FeCl3​ gives a violet/purple colour with phenolic compounds due to formation of a coloured ferric-phenolate complex.

    This confirms that XXX is a phenol.

  4. Conclusion

    Therefore, the correct option must be the one corresponding to phenol.

  5. Compare with stored answer

    The stored correct answer is B. Since the phenol option is intended here, this matches.

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