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Correct answer: 2
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Identify the target alcohol
The required product is 2-methylpropan-2-ol, whose structure is:
This is a tertiary alcohol.
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Reaction of an ester with Grignard reagent
Ethyl ethanoate is:
Esters react with Grignard reagents in such a way that 2 moles of Grignard reagent are needed per mole of ester to finally give a tertiary alcohol.
General reaction:
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Apply to the given case
Here:
- Ester:
- Grignard reagent:
First mole of adds to the ester carbonyl, and after elimination of , a ketone is formed: This ketone is propanone (acetone).
Then a second mole of adds to propanone:
On hydrolysis:
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Mole ratio
Thus, to form 1 mole of from 1 mole of ethyl ethanoate, required moles of are:
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Final integer answer
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Comparison with stored answer
Stored correct answer = 2, which matches the derived result.
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