JEE MainChemistryAlcohols Phenols and EthersNumerical+4 / −1
The number of chiral alcohol(s) with molecular formula is .
Numerical answer
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Correct answer: 1
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We need to count chiral alcohols having molecular formula .
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First, list all alcohol isomers of (exclude ethers, since the question asks only alcohols).
For , the alcohol isomers are:
- Butan-1-ol:
- Butan-2-ol:
- 2-Methylpropan-1-ol:
- 2-Methylpropan-2-ol:
- Now check chirality of each alcohol.
(i) Butan-1-ol
Structure:
No carbon has four different substituents. So, it is achiral.
(ii) Butan-2-ol
Structure:
The second carbon is attached to:
These are four different groups, so this carbon is a chiral center. Hence, butan-2-ol is chiral.
(iii) 2-Methylpropan-1-ol
Structure:
The central carbon is attached to:
Since two groups are identical ( and ), it is not chiral.
(iv) 2-Methylpropan-2-ol
Structure:
The central carbon is attached to three identical groups, so it is achiral.
- Therefore, only one alcohol structure is chiral:
- Butan-2-ol
- Note: Butan-2-ol exists as two enantiomers and , but the question asks for the number of chiral alcohol(s), i.e. the number of chiral compounds/structures, not stereoisomers counted separately unless explicitly stated.
So the required number is:
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