JEE MainChemistryAlcohols Phenols and EthersMCQ+4 / −1
Compound I is heated with Conc. HI to give a hydroxy compound A which is further heated with Zn dust to give compound B. Identify A and B. 

- A

- B

- C

- D

View written solutionFree
Correct answer: D
-
Interpret the reaction sequence
The statement says:
- Compound I on heating with concentrated HI gives a hydroxy compound A.
- Compound A on heating with Zn dust gives compound B.
A very standard organic transformation is:
- Phenyl ethers on cleavage with concentrated HI give phenol as one product.
- Phenol on distillation with zinc dust gets reduced to benzene.
-
Key reaction involved in the second step
The reaction of phenol with zinc dust is:
So if compound gives compound with Zn dust, then most likely:
-
Consistency with the first step
Concentrated HI cleaves aryl-alkyl ethers at the alkyl–O bond, producing phenol:
Hence compound I must be some aryl ether, and the hydroxy compound formed is indeed phenol.
-
Identify A and B
Therefore,
-
Match with the given options
Since the stored correct answer is D, the option corresponding to
must be Option D.
-
Final conclusion
Hence, the correct option is:
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