JEE MainChemistryAlcohols Phenols and EthersNumerical+4 / −1
Compound 'P' on nitration with dil. yields two isomers (A) and (B). These isomers can be separated by steam distillation. Isomers (A) and (B) show the intramolecular and intermolecular hydrogen bonding respectively. Compound (P) on reaction with conc. yields a yellow compound 'C', a strong acid. The number of oxygen atoms is present in compound 'C' .
Numerical answer
View written solutionFree
Correct answer: 7
- Identify compound from the nitration behavior
A compound which on nitration with dilute gives two isomers that can be separated by steam distillation, where one shows intramolecular hydrogen bonding and the other intermolecular hydrogen bonding, is phenol.
On mononitration of phenol, we get:
- -nitrophenol: shows intramolecular H-bonding
- -nitrophenol: shows intermolecular H-bonding
These can be separated by steam distillation because -nitrophenol is steam volatile.
So,
- Reaction of phenol with concentrated
Phenol with concentrated nitric acid gives 2,4,6-trinitrophenol, commonly called picric acid.
The reaction is:
This is a yellow compound and a strong acid, matching the description of compound .
- Count oxygen atoms in compound
Picric acid = 2,4,6-trinitrophenol
Its structure contains:
- one phenolic group oxygen
- three nitro groups , each containing oxygen atoms
So total oxygen atoms:
- Final answer
The number of oxygen atoms in compound is:
More from Alcohols Phenols and Ethers
- Consider the above reaction sequence and identify the product B. Includes diagram2022 · MCQ
- In the above reaction product B is : Includes diagram2022 · MCQ
- In the following reaction The yield for reaction I is and that of reaction II is . The overall yield of the complete reaction is . [nearest integer] Includes diagram2022 · Numerical
- Match List-I with List-II. Choose the correct answer from the options given below : Includes table Includes diagram2022 · MCQ
- Identify the major products A and B for the below given reaction sequence. Includes diagram2022 · MCQ
- Choose the correct option for the following reactions. Includes diagram2022 · MCQ
- Compound I is heated with Conc. HI to give a hydroxy compound A which is further heated with Zn dust to give compound B. Identify A and B. Includes diagram2022 · MCQ
- The major product (P) of the given reaction is (where, Me is ) Includes diagram2022 · MCQ