Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Alcohols Phenols and Ethers question

2022 · 26 Jul · Shift 2 · Q8
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Alcohols Phenols and Ethers
  5. /2022 · 26 Jul · Shift 2 · Q8

Alcohols Phenols and Ethers question

2022 · 26 Jul · Shift 2 · Q8

JEE MainChemistryAlcohols Phenols and EthersMCQ+4 / −1
Hydrolysis of which compound will give carbolic acid?
  1. A
    Cumene
  2. B
    Benzenediazonium chloride
  3. C
    Benzal chloride
  4. D
    Ethylene glycol ketal
View written solutionFree

Correct answer: B

  1. Identify what “carbolic acid” means

    Carbolic acid is the common name for phenol, i.e. C6H5OH\mathrm{C_6H_5OH}C6​H5​OH.

  2. Check each option for hydrolysis

    Option A: Cumene

    Cumene is isopropyl benzene, C6H5CH(CH3)2\mathrm{C_6H_5CH(CH_3)_2}C6​H5​CH(CH3​)2​.

    • On oxidation, cumene gives cumene hydroperoxide, which on acid cleavage gives phenol.
    • But simple hydrolysis of cumene does not give phenol.

    So, A is incorrect.

    Option B: Benzenediazonium chloride

    Benzenediazonium chloride is C6H5N2+Cl−\mathrm{C_6H_5N_2^+Cl^-}C6​H5​N2+​Cl−.

    On hydrolysis (usually warming with water):

    C6H5N2+Cl−+H2O→C6H5OH+N2+HCl\mathrm{C_6H_5N_2^+Cl^- + H_2O \rightarrow C_6H_5OH + N_2 + HCl}C6​H5​N2+​Cl−+H2​O→C6​H5​OH+N2​+HCl

    This directly gives phenol (carbolic acid).

    So, B is correct.

    Option C: Benzal chloride

    Benzal chloride is C6H5CHCl2\mathrm{C_6H_5CHCl_2}C6​H5​CHCl2​.

    Gem-dihalides on hydrolysis form carbonyl compounds. Thus:

    C6H5CHCl2→hydrolysisC6H5CHO\mathrm{C_6H_5CHCl_2 \xrightarrow{hydrolysis} C_6H_5CHO}C6​H5​CHCl2​hydrolysis​C6​H5​CHO

    Product is benzaldehyde, not phenol.

    So, C is incorrect.

    Option D: Ethylene glycol ketal

    Ketals on hydrolysis regenerate the parent carbonyl compound and ethylene glycol.

    They do not give phenol.

    So, D is incorrect.

  3. Final conclusion

    The compound whose hydrolysis gives carbolic acid (phenol) is:

    B: Benzenediazonium chloride\boxed{\text{B: Benzenediazonium chloride}}B: Benzenediazonium chloride​
  4. Comparison with stored correct answer

    Stored correct answer = B.

    My derived answer also = B, so they agree.

PreviousNext

More from Alcohols Phenols and Ethers

  • Compound 'P' on nitration with dil. HNO3​ yields two isomers (A) and (B). These isomers can be separated by steam distillation. Isomers (A) and (B) show the intramolecular and intermolecular hydrogen bonding respectively. Compound (P) on…2022 · Numerical
  • Consider the above reaction sequence and identify the product B. Includes diagram2022 · MCQ
  • In the above reaction product B is : Includes diagram2022 · MCQ
  • In the following reaction The % yield for reaction I is 60% and that of reaction II is 50%. The overall yield of the complete reaction is ​%. [nearest integer] Includes diagram2022 · Numerical
  • Match List-I with List-II. Choose the correct answer from the options given below : Includes table Includes diagram2022 · MCQ
  • Identify the major products A and B for the below given reaction sequence. Includes diagram2022 · MCQ
  • Choose the correct option for the following reactions. Includes diagram2022 · MCQ
  • Compound I is heated with Conc. HI to give a hydroxy compound A which is further heated with Zn dust to give compound B. Identify A and B. Includes diagram2022 · MCQ