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Atoms and Nuclei question

2019 · Shift 1 · Q37
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Atoms and Nuclei question

2019 · Shift 1 · Q37

JEE AdvancedPhysicsAtoms and NucleiMCQ+3 / −1
In a radioactive sample, 1940K{}_{19}^{40}K1940​K nuclei either decay into stable 2040Ca{}_{20}^{40}Ca2040​Ca nuclei with decay constant 4.5 ×\times× 10-10 per year or into stable 1840Ar{}_{18}^{40}Ar1840​Ar nuclei with decay constant 0.5 ×\times× 10-10 per year. Given that in this sample all the stable 2040Ca{}_{20}^{40}Ca2040​Ca and 1840Ar{}_{18}^{40}Ar1840​Ar nuclei are produced by the 1940K{}_{19}^{40}K1940​K nuclei only. In time t ×\times× 109 years, if the ratio of the sum of stable 2040Ca{}_{20}^{40}Ca2040​Ca and 1840Ar{}_{18}^{40}Ar1840​Ar nuclei to the radioactive 1940K{}_{19}^{40}K1940​K nuclei is 99, the value of t will be [Given : In 10 = 2.3]
  1. A
    9.2
  2. B
    1.15
  3. C
    4.6
  4. D
    2.3
View written solutionFree

Correct answer: A

Step-by-Step Solution

  1. Understanding the Decay Process The radioactive nucleus 1940K{}_{19}^{40}K1940​K decays through two parallel paths into stable nuclei 2040Ca{}_{20}^{40}Ca2040​Ca and 1840Ar{}_{18}^{40}Ar1840​Ar. This is a case of parallel radioactive decay.

    • Decay 1: 1940K→2040Ca{}_{19}^{40}K \rightarrow {}_{20}^{40}Ca1940​K→2040​Ca with decay constant λCa=4.5×10−10\lambda_{Ca} = 4.5 \times 10^{-10}λCa​=4.5×10−10 per year.
    • Decay 2: 1940K→1840Ar{}_{19}^{40}K \rightarrow {}_{18}^{40}Ar1940​K→1840​Ar with decay constant λAr=0.5×10−10\lambda_{Ar} = 0.5 \times 10^{-10}λAr​=0.5×10−10 per year.
  2. Calculating the Total Decay Constant (λtotal\\\lambda_{total}λtotal​) For parallel decay, the total decay constant is the sum of the individual decay constants. λtotal=λCa+λAr\lambda_{total} = \lambda_{Ca} + \lambda_{Ar}λtotal​=λCa​+λAr​ λtotal=(4.5×10−10)+(0.5×10−10) per year\lambda_{total} = (4.5 \times 10^{-10}) + (0.5 \times 10^{-10}) \text{ per year}λtotal​=(4.5×10−10)+(0.5×10−10) per year λtotal=5.0×10−10 per year\lambda_{total} = 5.0 \times 10^{-10} \text{ per year}λtotal​=5.0×10−10 per year

  3. Radioactive Decay Law Let N0N_0N0​ be the initial number of 1940K{}_{19}^{40}K1940​K nuclei at time T=0T=0T=0. The number of 1940K{}_{19}^{40}K1940​K nuclei remaining at time TTT, denoted by NKN_KNK​, is given by the radioactive decay law: NK(T)=N0e−λtotalTN_K(T) = N_0 e^{-\lambda_{total} T}NK​(T)=N0​e−λtotal​T

  4. Relating Parent and Daughter Nuclei The problem states that all stable 2040Ca{}_{20}^{40}Ca2040​Ca and 1840Ar{}_{18}^{40}Ar1840​Ar nuclei are produced from the decay of 1940K{}_{19}^{40}K1940​K. Therefore, the total number of daughter nuclei is equal to the number of parent nuclei that have decayed. Number of decayed 1940K{}_{19}^{40}K1940​K nuclei = N0−NK(T)N_0 - N_K(T)N0​−NK​(T). Sum of stable daughter nuclei = NCa(T)+NAr(T)N_{Ca}(T) + N_{Ar}(T)NCa​(T)+NAr​(T). So, NCa(T)+NAr(T)=N0−NK(T)N_{Ca}(T) + N_{Ar}(T) = N_0 - N_K(T)NCa​(T)+NAr​(T)=N0​−NK​(T).

  5. Using the Given Ratio We are given that at a specific time TTT, the ratio of the sum of stable nuclei to the radioactive nuclei is 99. NCa(T)+NAr(T)NK(T)=99\frac{N_{Ca}(T) + N_{Ar}(T)}{N_K(T)} = 99NK​(T)NCa​(T)+NAr​(T)​=99 Substituting the expression from Step 4: N0−NK(T)NK(T)=99\frac{N_0 - N_K(T)}{N_K(T)} = 99NK​(T)N0​−NK​(T)​=99

  6. Solving for Time (T) Let's solve the equation from Step 5. N0NK(T)−1=99\frac{N_0}{N_K(T)} - 1 = 99NK​(T)N0​​−1=99 N0NK(T)=100\frac{N_0}{N_K(T)} = 100NK​(T)N0​​=100 Now, substitute the decay law from Step 3, NK(T)=N0e−λtotalTN_K(T) = N_0 e^{-\lambda_{total} T}NK​(T)=N0​e−λtotal​T. N0N0e−λtotalT=100\frac{N_0}{N_0 e^{-\lambda_{total} T}} = 100N0​e−λtotal​TN0​​=100 eλtotalT=100e^{\lambda_{total} T} = 100eλtotal​T=100 Taking the natural logarithm (ln) of both sides: ln⁡(eλtotalT)=ln⁡(100)\ln(e^{\lambda_{total} T}) = \ln(100)ln(eλtotal​T)=ln(100) λtotalT=ln⁡(102)=2ln⁡(10)\lambda_{total} T = \ln(10^2) = 2 \ln(10)λtotal​T=ln(102)=2ln(10) T=2ln⁡(10)λtotalT = \frac{2 \ln(10)}{\lambda_{total}}T=λtotal​2ln(10)​

  7. Numerical Calculation We are given ln⁡(10)=2.3\ln(10) = 2.3ln(10)=2.3 and we calculated λtotal=5.0×10−10\lambda_{total} = 5.0 \times 10^{-10}λtotal​=5.0×10−10 per year. T=2×2.35.0×10−10 yearsT = \frac{2 \times 2.3}{5.0 \times 10^{-10}} \text{ years}T=5.0×10−102×2.3​ years T=4.65.0×10−10 yearsT = \frac{4.6}{5.0 \times 10^{-10}} \text{ years}T=5.0×10−104.6​ years T=0.92×1010 yearsT = 0.92 \times 10^{10} \text{ years}T=0.92×1010 years T=9.2×109 yearsT = 9.2 \times 10^9 \text{ years}T=9.2×109 years

  8. Finding the value of 't' The problem states that the time is t×109t \times 10^9t×109 years. Comparing this with our calculated time TTT: t×109 years=9.2×109 yearst \times 10^9 \text{ years} = 9.2 \times 10^9 \text{ years}t×109 years=9.2×109 years t=9.2t = 9.2t=9.2

Therefore, the value of t is 9.2, which corresponds to option A.

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