- A
- B
- C
- D
View written solutionFree
Correct answer: A, B, C
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We need to check which given boron compounds react with ammonia to form boron nitride, .
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Recall some standard reactions of ammonia with boron compounds:
- Elemental boron reacts with ammonia on heating: So, A is correct.
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Check :
Diborane reacts with ammonia first to form an addition compound, which on heating gives borazine / related intermediates, and finally boron nitride is obtained on strong heating. Overall, diborane can give boron nitride with ammonia.
A simplified overall reaction is: Hence, B is correct.
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Check :
Boric oxide reacts with ammonia at high temperature to form boron nitride: So, C is correct.
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Check :
contains the tetrafluoroborate ion, . In presence of ammonia, it does not give boron nitride directly because the very stable bonds resist conversion to . Instead, acid-base reaction with ammonia would dominate.
Therefore, D is incorrect.
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Hence the compounds that react with to give are:
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Comparison with stored correct answer:
Stored correct answer = A, B, C
Our derived answer = A, B, C
So, the answers agree.
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