- AThe hypochlorite ion is the strongest conjugate base.
- BThe molecular shape of only chlorate ion is influenced by the lone pair of electrons of Cl.
- CThe hypochlorite and chlorate ions disproportionate to give rise to identical set of ions.
- DThe hypochlorite ion oxidises the sulphite ion.
View written solutionFree
Correct answer: A, B, D
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Identify the ions and oxidation states of chlorine
- Hypochlorite: , chlorine is in oxidation state .
- Chlorate: , chlorine is in oxidation state .
- Perchlorate: , chlorine is in oxidation state .
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Option A: The hypochlorite ion is the strongest conjugate base.
Compare the parent acids:
- (hypochlorous acid)
- (chloric acid)
- (perchloric acid)
Acid strength increases strongly with oxidation state / number of oxygens:
Therefore, conjugate base strength is the reverse order:
So, hypochlorite ion is the strongest conjugate base.
✅ A is correct.
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Option B: The molecular shape of only chlorate ion is influenced by the lone pair of electrons of Cl.
Let us examine shapes:
- Hypochlorite, : diatomic ion, so molecular shape discussion in terms of bond angle distortion by lone pair is not meaningful.
- Chlorate, : central Cl has three bonded oxygens and one lone pair, so electron pair geometry is tetrahedral and molecular shape is trigonal pyramidal. Hence shape is influenced by a lone pair.
- Perchlorate, : four bonded oxygens, no lone pair on central Cl in VSEPR description; shape is tetrahedral.
Thus, among these three ions, only chlorate ion has its molecular shape influenced by a lone pair on Cl.
✅ B is correct.
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Option C: The hypochlorite and chlorate ions disproportionate to give rise to identical set of ions.
Check disproportionation reactions.
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Hypochlorite disproportionation: Products: and
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Chlorate disproportionation: chlorine in state can disproportionate to a lower and higher oxidation state, typically giving Products: and
The product sets are not identical.
❌ C is incorrect.
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Option D: The hypochlorite ion oxidises the sulphite ion.
Sulphite ion is , where sulfur is in oxidation state . It can be oxidised to sulfate, , where sulfur is in oxidation state .
Hypochlorite (, Cl at ) is a known oxidising agent and can be reduced to chloride (, Cl at ).
A representative redox process is:
This is balanced in atoms and charge:
- Left charge:
- Right charge:
Hence hypochlorite indeed oxidises sulphite to sulfate.
✅ D is correct.
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Final selection
Correct statements are:
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Comparison with stored correct answer
Stored correct answer: A, B, D
My derived answer matches exactly.
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