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P Block Elements question

2020 · Shift 1 · Q11
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P Block Elements question

2020 · Shift 1 · Q11

JEE AdvancedChemistryP Block ElementsMultiple correct+4 / −2
With respect to hypochlorite, chlorate and perchlorate ions, choose the correct statement(s).
  1. A
    The hypochlorite ion is the strongest conjugate base.
  2. B
    The molecular shape of only chlorate ion is influenced by the lone pair of electrons of Cl.
  3. C
    The hypochlorite and chlorate ions disproportionate to give rise to identical set of ions.
  4. D
    The hypochlorite ion oxidises the sulphite ion.
View written solutionFree

Correct answer: A, B, D

  1. Identify the ions and oxidation states of chlorine

    • Hypochlorite: ClO−\mathrm{ClO^-}ClO−, chlorine is in oxidation state +1+1+1.
    • Chlorate: ClO3−\mathrm{ClO_3^-}ClO3−​, chlorine is in oxidation state +5+5+5.
    • Perchlorate: ClO4−\mathrm{ClO_4^-}ClO4−​, chlorine is in oxidation state +7+7+7.
  2. Option A: The hypochlorite ion is the strongest conjugate base.

    Compare the parent acids:

    • HClO\mathrm{HClO}HClO (hypochlorous acid)
    • HClO3\mathrm{HClO_3}HClO3​ (chloric acid)
    • HClO4\mathrm{HClO_4}HClO4​ (perchloric acid)

    Acid strength increases strongly with oxidation state / number of oxygens: HClO4>HClO3>HClO\mathrm{HClO_4 > HClO_3 > HClO}HClO4​>HClO3​>HClO

    Therefore, conjugate base strength is the reverse order: ClO−>ClO3−>ClO4−\mathrm{ClO^- > ClO_3^- > ClO_4^-}ClO−>ClO3−​>ClO4−​

    So, hypochlorite ion is the strongest conjugate base.

    ✅ A is correct.

  3. Option B: The molecular shape of only chlorate ion is influenced by the lone pair of electrons of Cl.

    Let us examine shapes:

    • Hypochlorite, ClO−\mathrm{ClO^-}ClO−: diatomic ion, so molecular shape discussion in terms of bond angle distortion by lone pair is not meaningful.
    • Chlorate, ClO3−\mathrm{ClO_3^-}ClO3−​: central Cl has three bonded oxygens and one lone pair, so electron pair geometry is tetrahedral and molecular shape is trigonal pyramidal. Hence shape is influenced by a lone pair.
    • Perchlorate, ClO4−\mathrm{ClO_4^-}ClO4−​: four bonded oxygens, no lone pair on central Cl in VSEPR description; shape is tetrahedral.

    Thus, among these three ions, only chlorate ion has its molecular shape influenced by a lone pair on Cl.

    ✅ B is correct.

  4. Option C: The hypochlorite and chlorate ions disproportionate to give rise to identical set of ions.

    Check disproportionation reactions.

    • Hypochlorite disproportionation: 3ClO−→2Cl−+ClO3−3\mathrm{ClO^-} \rightarrow 2\mathrm{Cl^-} + \mathrm{ClO_3^-}3ClO−→2Cl−+ClO3−​ Products: Cl−\mathrm{Cl^-}Cl− and ClO3−\mathrm{ClO_3^-}ClO3−​

    • Chlorate disproportionation: chlorine in +5+5+5 state can disproportionate to a lower and higher oxidation state, typically giving 4ClO3−→3ClO4−+Cl−4\mathrm{ClO_3^-} \rightarrow 3\mathrm{ClO_4^-} + \mathrm{Cl^-}4ClO3−​→3ClO4−​+Cl− Products: Cl−\mathrm{Cl^-}Cl− and ClO4−\mathrm{ClO_4^-}ClO4−​

    The product sets are not identical.

    ❌ C is incorrect.

  5. Option D: The hypochlorite ion oxidises the sulphite ion.

    Sulphite ion is SO32−\mathrm{SO_3^{2-}}SO32−​, where sulfur is in oxidation state +4+4+4. It can be oxidised to sulfate, SO42−\mathrm{SO_4^{2-}}SO42−​, where sulfur is in oxidation state +6+6+6.

    Hypochlorite (ClO−\mathrm{ClO^-}ClO−, Cl at +1+1+1) is a known oxidising agent and can be reduced to chloride (Cl−\mathrm{Cl^-}Cl−, Cl at −1-1−1).

    A representative redox process is: ClO−+SO32−→Cl−+SO42−\mathrm{ClO^- + SO_3^{2-} \rightarrow Cl^- + SO_4^{2-}}ClO−+SO32−​→Cl−+SO42−​

    This is balanced in atoms and charge:

    • Left charge: −1+(−2)=−3-1 + (-2) = -3−1+(−2)=−3
    • Right charge: −1+(−2)=−3-1 + (-2) = -3−1+(−2)=−3

    Hence hypochlorite indeed oxidises sulphite to sulfate.

    ✅ D is correct.

  6. Final selection

    Correct statements are: A, B, D\boxed{\text{A, B, D}}A, B, D​

  7. Comparison with stored correct answer

    Stored correct answer: A, B, D

    My derived answer matches exactly.

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