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Correct answer: 4.77 G
- Identify the gas formed
White phosphorus reacts with hot aqueous NaOH in inert atmosphere to give phosphine gas:
Balancing properly:
Check phosphorus balance: left has P, right has P, so it is balanced.
Thus, gas is .
- Calculate moles of white phosphorus
White phosphorus is .
Molar mass of :
Given mass:
So moles of are:
- Find moles of phosphine produced
From the reaction,
Hence,
- Reaction of phosphine with copper sulfate
Phosphine reacts with to form copper phosphide:
From this stoichiometry,
So,
Therefore for mol :
- Calculate mass of required
Molar mass of :
Mass required:
- Final answer
Required amount of is:
As an integer-type style entry, this corresponds to about g, but numerically the exact value is g.
- Comparison with stored answer
Stored correct answer is to , which is approximately half of the derived value.
My stoichiometric derivation gives , so I disagree with the stored answer. The likely issue is that the stored answer may have used an incorrect reaction ratio for and or an incorrect phosphorus-to-phosphine relation.
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