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P Block Elements question

2022 · Shift 1 · Q5
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P Block Elements question

2022 · Shift 1 · Q5

JEE AdvancedChemistryP Block ElementsNumerical+3 / −1
Dissolving 1.24 g1.24 \mathrm{~g}1.24 g of white phosphorous in boiling NaOH\mathrm{NaOH}NaOH solution in an inert atmosphere gives a gas Q\mathbf{Q}Q. The amount of CuSO4\mathrm{CuSO}_{4}CuSO4​(in g) required to completely consume the gas Q\mathbf{Q}Q is ‾\underline{\hspace{2cm}}​. [Given: Atomic mass of H=1,O=16,Na=23,P=31, S=32,Cu=63\mathrm{H}=1, \mathrm{O}=16, \mathrm{Na}=23, \mathrm{P}=31, \mathrm{~S}=32, \mathrm{Cu}=63H=1,O=16,Na=23,P=31, S=32,Cu=63 ]
Numerical answer
View written solutionFree

Correct answer: 4.77 G

  1. Identify the gas formed

White phosphorus reacts with hot aqueous NaOH in inert atmosphere to give phosphine gas:

P4+3NaOH+3H2O→PH3+3NaH2PO2P_4 + 3NaOH + 3H_2O \rightarrow PH_3 + 3NaH_2PO_2P4​+3NaOH+3H2​O→PH3​+3NaH2​PO2​

Balancing properly:

P4+3NaOH+3H2O→PH3+3NaH2PO2P_4 + 3NaOH + 3H_2O \rightarrow PH_3 + 3NaH_2PO_2P4​+3NaOH+3H2​O→PH3​+3NaH2​PO2​

Check phosphorus balance: left has 444 P, right has 1+3=41+3=41+3=4 P, so it is balanced.

Thus, gas QQQ is PH3PH_3PH3​.


  1. Calculate moles of white phosphorus

White phosphorus is P4P_4P4​.

Molar mass of P4P_4P4​:

4×31=124 g mol−14 \times 31 = 124\,\text{g mol}^{-1}4×31=124g mol−1

Given mass:

1.24 g1.24\,\text{g}1.24g

So moles of P4P_4P4​ are:

n(P4)=1.24124=0.01 moln(P_4)=\frac{1.24}{124}=0.01\,\text{mol}n(P4​)=1241.24​=0.01mol


  1. Find moles of phosphine produced

From the reaction,

1 mol P4→1 mol PH31\text{ mol }P_4 \rightarrow 1\text{ mol }PH_31 mol P4​→1 mol PH3​

Hence,

n(PH3)=0.01 moln(PH_3)=0.01\,\text{mol}n(PH3​)=0.01mol


  1. Reaction of phosphine with copper sulfate

Phosphine reacts with CuSO4CuSO_4CuSO4​ to form copper phosphide:

2PH3+6CuSO4→2H3PO4+Cu3P2+6H2SO42PH_3 + 6CuSO_4 \rightarrow 2H_3PO_4 + Cu_3P_2 + 6H_2SO_42PH3​+6CuSO4​→2H3​PO4​+Cu3​P2​+6H2​SO4​

From this stoichiometry,

2 mol PH3 require 6 mol CuSO42\text{ mol }PH_3 \text{ require } 6\text{ mol }CuSO_42 mol PH3​ require 6 mol CuSO4​

So,

1 mol PH3 requires 3 mol CuSO41\text{ mol }PH_3 \text{ requires } 3\text{ mol }CuSO_41 mol PH3​ requires 3 mol CuSO4​

Therefore for 0.010.010.01 mol PH3PH_3PH3​:

n(CuSO4)=3×0.01=0.03 moln(CuSO_4)=3\times 0.01=0.03\,\text{mol}n(CuSO4​)=3×0.01=0.03mol


  1. Calculate mass of CuSO4CuSO_4CuSO4​ required

Molar mass of CuSO4CuSO_4CuSO4​:

63+32+4(16)=63+32+64=159 g mol−163+32+4(16)=63+32+64=159\,\text{g mol}^{-1}63+32+4(16)=63+32+64=159g mol−1

Mass required:

m=0.03×159=4.77 gm=0.03\times 159=4.77\,\text{g}m=0.03×159=4.77g


  1. Final answer

Required amount of CuSO4CuSO_4CuSO4​ is:

4.77 g\boxed{4.77\,\text{g}}4.77g​

As an integer-type style entry, this corresponds to about 4.84.84.8 g, but numerically the exact value is 4.774.774.77 g.


  1. Comparison with stored answer

Stored correct answer is 2.372.372.37 to 2.412.412.41, which is approximately half of the derived value.

My stoichiometric derivation gives 4.77 g4.77\,\text{g}4.77g, so I disagree with the stored answer. The likely issue is that the stored answer may have used an incorrect reaction ratio for PH3PH_3PH3​ and CuSO4CuSO_4CuSO4​ or an incorrect phosphorus-to-phosphine relation.

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