- ADry O .
- BA mixture of O and N .
- CMoist O .
- DO in the presence of aqueous NaOH.
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Correct answer: B
-
Identify the product required
We need the reagent/condition such that:
is phosphorus(III) oxide (formed when phosphorus burns in a limited supply of oxygen).
-
Recall the relevant reactions of phosphorus with oxygen
- In excess oxygen:
- In limited oxygen:
So, to obtain selectively, oxygen must be available in a restricted amount, not in excess.
-
Evaluate each option
Option A: Dry
Pure dry oxygen provides abundant oxygen. Phosphorus burns vigorously and tends to form the higher oxide: So this is not selective for .
Option B: A mixture of and
Mixing with inert effectively dilutes oxygen, creating a limited oxygen atmosphere. Under such controlled oxygen supply, phosphorus forms: Hence this option is correct.
Option C: Moist
Moisture is not suitable because phosphorus oxides can undergo hydrolysis, and oxygen is still available. This will not selectively give pure .
Option D: in the presence of aqueous NaOH
In aqueous/basic medium, phosphorus and its oxides can undergo side reactions/disproportionation or hydrolysis. This is not a condition for selective formation of .
-
Conclusion
The correct condition is a diluted oxygen atmosphere, i.e. a mixture of and .
Therefore, the correct answer is:
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