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Ionic Equilibrium

19 questions · Chemistry · JEE Advanced
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Ionic Equilibrium

19 questions · Chemistry · JEE Advanced

  1. At 25 °C, the concentration of H+ ions in 1.00 × 10−3 M aqueous solution of a weak monobasic acid having acid dissociation constant (Ka) of 4.00 × 10−11 is X × 10−7 M. The value of X is ​. Use: Ionic product of…2025 · Shift 1 · Q9 · Numerical
  2. The solubility of barium iodate in an aqueous solution prepared by mixing 200 mL of 0.010 M barium nitrate with 100 mL of 0.10 M sodium iodate is X×10−6 moldm−3. The value of X…2025 · Shift 2 · Q10 · Numerical
  3. On decreasing the pH from 7 to 2 , the solubility of a sparingly soluble salt (MX) of a weak acid (HX) increased from 10−4 mol L−1 to 10−3 mol L−1. The p Ka​…2023 · Shift 1 · Q6 · MCQ
  4. A solution is prepared by mixing 0.01 mol each of H2​CO3​,NaHCO3​,Na2​CO3​, and NaOH in 100 mL of water. pH of the resulting…2022 · Shift 1 · Q3 · Numerical
  5. Concentration of H2​SO4​ and Na2​SO4​ in a solution is 1M and 1.8×10−2M, respectively. Molar solubility of PbSO4​ in the same solution is X×10−YM…2022 · Shift 2 · Q1 · Numerical
  6. A solution of 0.1 M weak base (B) is titrated with 0.1 M of a strong acid (HA). The variation of pH of the solution with the volume of HA added is shown in the figure below. What is the pKb of the base? The neutralisation reaction is given… Includes diagram2020 · Shift 2 · Q13 · Numerical
  7. An acidified solution of 0.05 M Zn2+ is saturated with 0.1 M H2​S. What is the minimum molar concentration (M) of H+ required to prevent the precipitation of ZnS? Use Ksp(ZnS) = 1.25 × 10 − 22 and overall…2020 · Shift 2 · Q18 · Numerical
  8. The solubility of a salt of weak acid (AB) at pH3 is Y×10−3molL−1. The value of Y is ​. (Given that the value of solubility product of AB (Ksp​)=2×10−10…2018 · Shift 1 · Q9 · Numerical
  9. Dilution processes of different aqueous solutions, with water, are given in LIST - I. The effects of dilution of the solutions on [H+] are given in LIST - II (Note: Degree of dissociation (a) of weak acid and weak… Includes table2018 · Shift 2 · Q15 · MCQ
  10. Paragraph When 100 mL of 1.0 M KCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a temperature increase of 5.7o C was measured for the beaker and its contents (Expt. 1). Because the enthalpy of…2015 · Shift 2 · Q5 · Multiple correct
  11. Paragraph When 100 mL of 1.0 M HCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a temperature increase of 5.7o C was measured for the beaker and its contents (Expt. 1). Because the enthalpy of…2015 · Shift 2 · Q6 · Multiple correct
  12. The initial rate of hydrolysis of methyl acetate (1M) by a weak acid (HA, 1M) is 1/100th of that of a strong acid (HX, 1M), at 25oC. The Ka of HA is2013 · Shift 1 · Q4 · Multiple correct
  13. The Ksp of Ag2​CrO4​ is 1.1 × 10-12 at 298 K. The solubility (in mol/L) of Ag2​CrO4​ in a 0.1 M AgNO3​ solution is2013 · Shift 2 · Q6 · Multiple correct
  14. In 1 L saturated solution of AgCl [Ksp(AgCl) = 1.6 × 10-10], 0.1 mol of CuCl [Ksp(CuCl) = 1.0 × 10-6] is added. The resultant concentration of Ag+ in the solution is 1.6 × 10-x. The value of "x" is2011 · Shift 2 · Q6 · Numerical
  15. Aqueous solution of HNO3​, KOH and CH3​COOH and CH3​COONa of identical concentrations are provided. The pairs of solutions which form a buffer upon mixing is(are)2010 · Shift 1 · Q4 · Multiple correct
  16. Amongst the following the total number of compounds whose aqueous solution turns red litmus paper blue is KCN, K2​SO4​, (NH4​)2​C2​O4​, NaCl, Zn(NO3​)2​, FeCl3​, K2​CO3​, NH4​NO3​ and LiCN2010 · Shift 1 · Q5 · Numerical
  17. The dissociation constant of a substituted benzoic acid at 25 ∘ C is 1.0 × 10 −4. The pH of a 0.01 M solution of its sodium salt is ​.2009 · Shift 2 · Q14 · Numerical
  18. 2.5 mL of 52​ M weak monoacidic base (K b​= 1 × 10 −12 at 25 ∘ C) is titrated with 152​ M HCl in water at 25 ∘ C. The concentration of H + at equivalence point is (K w​= 1 ×…2008 · Shift 1 · Q7 · MCQ
  19. Solubility product constants (K sp​) of salts of types MX, MX 2​ and M 3​ X at temperature T are 4.0 × 10 −8, 3.2 × 10 −14 and 2.7 × 10 −15, respectively. Solubilities (mol dm −3…2008 · Shift 2 · Q10 · MCQ