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Correct answer: 6
The user wants to find the total number of black coloured sulphides from the given list: , , , , , , , and .
This problem requires knowledge of the characteristic colours of common metal sulphides, a topic frequently covered in qualitative inorganic analysis.
Let's determine the colour of each sulphide one by one:
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(Lead(II) sulphide): This is a well-known precipitate in qualitative analysis (Group II cations). It is black.
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(Copper(II) sulphide): Also a Group II cation precipitate, it is black.
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(Mercury(II) sulphide): When precipitated from a solution using , it forms a black solid (metacinnabar). Although a more stable red form (cinnabar) exists, the common precipitate is black.
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(Manganese(II) sulphide): This is a Group IV cation precipitate. It has a characteristic buff or flesh-pink colour.
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(Silver(I) sulphide): This is the compound responsible for the tarnishing of silver. It is black.
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(Nickel(II) sulphide): A Group IV cation precipitate, it is black.
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(Cobalt(II) sulphide): Similar to , it is a Group IV cation precipitate and is black.
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(Bismuth(III) sulphide): A Group II cation precipitate. It is described as dark brown or brownish-black. For the purpose of strict colour classification, it is not considered pure black.
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(Tin(IV) sulphide): This is known as 'mosaic gold' and has a characteristic golden-yellow colour.
Now, let's list the sulphides and their colours:
- : Black
- : Black
- : Black
- : Buff/Pink (Not black)
- : Black
- : Black
- : Black
- : Dark Brown (Not black)
- : Yellow (Not black)
Counting the sulphides that are explicitly black: , , , , , and .
There are a total of 6 black coloured sulphides in the given list.
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