Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

D and F Block Elements question

2014 · Shift 1 · Q19
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Advanced
  3. /Chemistry
  4. /D and F Block Elements
  5. /2014 · Shift 1 · Q19

D and F Block Elements question

2014 · Shift 1 · Q19

JEE AdvancedChemistryD and F Block ElementsNumerical+3 / −1
Among PbSPbSPbS, CuSCuSCuS, HgSHgSHgS, MnSMnSMnS, Ag2SAg_2SAg2​S, NiSNiSNiS, CoSCoSCoS, Bi2S3Bi_2S_3Bi2​S3​ and SnS2SnS_2SnS2​ the total number of black coloured sulphides is
Numerical answer
View written solutionFree

Correct answer: 6

The user wants to find the total number of black coloured sulphides from the given list: PbSPbSPbS, CuSCuSCuS, HgSHgSHgS, MnSMnSMnS, Ag2SAg_2SAg2​S, NiSNiSNiS, CoSCoSCoS, Bi2S3Bi_2S_3Bi2​S3​ and SnS2SnS_2SnS2​.

This problem requires knowledge of the characteristic colours of common metal sulphides, a topic frequently covered in qualitative inorganic analysis.

Let's determine the colour of each sulphide one by one:

  1. PbSPbSPbS (Lead(II) sulphide): This is a well-known precipitate in qualitative analysis (Group II cations). It is black.

  2. CuSCuSCuS (Copper(II) sulphide): Also a Group II cation precipitate, it is black.

  3. HgSHgSHgS (Mercury(II) sulphide): When precipitated from a solution using H2SH_2SH2​S, it forms a black solid (metacinnabar). Although a more stable red form (cinnabar) exists, the common precipitate is black.

  4. MnSMnSMnS (Manganese(II) sulphide): This is a Group IV cation precipitate. It has a characteristic buff or flesh-pink colour.

  5. Ag2SAg_2SAg2​S (Silver(I) sulphide): This is the compound responsible for the tarnishing of silver. It is black.

  6. NiSNiSNiS (Nickel(II) sulphide): A Group IV cation precipitate, it is black.

  7. CoSCoSCoS (Cobalt(II) sulphide): Similar to NiSNiSNiS, it is a Group IV cation precipitate and is black.

  8. Bi2S3Bi_2S_3Bi2​S3​ (Bismuth(III) sulphide): A Group II cation precipitate. It is described as dark brown or brownish-black. For the purpose of strict colour classification, it is not considered pure black.

  9. SnS2SnS_2SnS2​ (Tin(IV) sulphide): This is known as 'mosaic gold' and has a characteristic golden-yellow colour.

Now, let's list the sulphides and their colours:

  • PbSPbSPbS: Black
  • CuSCuSCuS: Black
  • HgSHgSHgS: Black
  • MnSMnSMnS: Buff/Pink (Not black)
  • Ag2SAg_2SAg2​S: Black
  • NiSNiSNiS: Black
  • CoSCoSCoS: Black
  • Bi2S3Bi_2S_3Bi2​S3​: Dark Brown (Not black)
  • SnS2SnS_2SnS2​: Yellow (Not black)

Counting the sulphides that are explicitly black: PbSPbSPbS, CuSCuSCuS, HgSHgSHgS, Ag2SAg_2SAg2​S, NiSNiSNiS, and CoSCoSCoS.

There are a total of 6 black coloured sulphides in the given list.

PreviousNext

More from D and F Block Elements

  • The pair(s) of reagents that yield paramagnetic species is/are2014 · Multiple correct
  • Upon treatment with ammoniacal H2​S, the metal ion that precipitates as a sulphide is2013 · MCQ
  • The colour of light absorbed by an aqueous solution of CuSO4​ is2012 · MCQ
  • For the given aqueous reactions, which of the statement(s) is(are) true? Includes diagram2012 · Multiple correct
  • The oxidation number of Mn in the product of alkaline oxidative fusion of MnO 2​ is ​.2009 · Numerical
  • The pair(s) of diamagnetic ions is(are)2025 · Multiple correct
  • In the scheme given below, X and Y, respectively, are Includes diagram2023 · MCQ
  • The treatment of galena with HNO3​ produces a gas that is2022 · Multiple correct