JEE AdvancedChemistryD and F Block ElementsMCQ+3 / −1
In the scheme given below, and , respectively, are 

- Aand
- Band
- Cand
- Dand
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Correct answer: C
-
The options suggest that the reaction scheme involves a manganese species being converted under oxidation conditions, with a halogen/hypohalite involved.
-
Among common manganese oxyanions:
- is permanganate, where Mn is in oxidation state .
- is manganate, where Mn is in oxidation state .
- is chromate, not a manganese species.
-
A very standard preparation in inorganic chemistry is oxidation of manganate to permanganate using chlorine:
Let us verify oxidation states:
- Mn goes from in to in , so it is oxidized.
- goes from to in , so chlorine is reduced.
This reaction is perfectly consistent with a scheme where:
- (product formed)
- (oxidizing/reagent species in the scheme)
-
Now check options systematically:
A: and
- Chromate is unrelated to the usual manganese conversion here.
- Not consistent.
B: and
- This would assign as manganate, but the standard oxidation by chlorine gives permanganate as product, not manganate.
- So this is not the best fit.
C: and
- Matches the known reaction above.
- Correct.
D: and
- contains Mn in state and does not fit the typical oxyanion interconversion suggested by the options.
- Not correct.
-
Therefore,
Hence, the correct option is C.
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