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D and F Block Elements question

2023 · Shift 1 · Q4
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D and F Block Elements question

2023 · Shift 1 · Q4

JEE AdvancedChemistryD and F Block ElementsMCQ+3 / −1
In the scheme given below, X\mathbf{X}X and Y\mathbf{Y}Y, respectively, are JEE Advanced 2023 Paper 1 Online Chemistry - d and f Block Elements Question 2 English
  1. A
    CrO42−\mathrm{CrO}_4{ }^{2-}CrO4​2− and Br2\mathrm{Br}_2Br2​
  2. B
    MnO42−\mathrm{MnO}_4{ }^{2-}MnO4​2− and Cl2\mathrm{Cl}_2Cl2​
  3. C
    MnO4−\mathrm{MnO}_4{ }^{-}MnO4​− and Cl2\mathrm{Cl}_2Cl2​
  4. D
    MnSO4\mathrm{MnSO}_4MnSO4​ and HOCl\mathrm{HOCl}HOCl
View written solutionFree

Correct answer: C

  1. The options suggest that the reaction scheme involves a manganese species being converted under oxidation conditions, with a halogen/hypohalite involved.

  2. Among common manganese oxyanions:

    • MnO4− \mathrm{MnO_4^-}MnO4−​ is permanganate, where Mn is in oxidation state +7+7+7.
    • MnO42−\mathrm{MnO_4^{2-}}MnO42−​ is manganate, where Mn is in oxidation state +6+6+6.
    • CrO42−\mathrm{CrO_4^{2-}}CrO42−​ is chromate, not a manganese species.
  3. A very standard preparation in inorganic chemistry is oxidation of manganate to permanganate using chlorine: 2 MnO42−+Cl2→2 MnO4−+2 Cl−2\,\mathrm{MnO_4^{2-}} + \mathrm{Cl_2} \rightarrow 2\,\mathrm{MnO_4^-} + 2\,\mathrm{Cl^-}2MnO42−​+Cl2​→2MnO4−​+2Cl−

    Let us verify oxidation states:

    • Mn goes from +6+6+6 in MnO42−\mathrm{MnO_4^{2-}}MnO42−​ to +7+7+7 in MnO4−\mathrm{MnO_4^-}MnO4−​, so it is oxidized.
    • Cl2\mathrm{Cl_2}Cl2​ goes from 000 to −1-1−1 in Cl−\mathrm{Cl^-}Cl−, so chlorine is reduced.

    This reaction is perfectly consistent with a scheme where:

    • X=MnO4−X = \mathrm{MnO_4^-}X=MnO4−​ (product formed)
    • Y=Cl2Y = \mathrm{Cl_2}Y=Cl2​ (oxidizing/reagent species in the scheme)
  4. Now check options systematically:

    A: CrO42−\mathrm{CrO_4^{2-}}CrO42−​ and Br2\mathrm{Br_2}Br2​

    • Chromate is unrelated to the usual manganese conversion here.
    • Not consistent.

    B: MnO42−\mathrm{MnO_4^{2-}}MnO42−​ and Cl2\mathrm{Cl_2}Cl2​

    • This would assign XXX as manganate, but the standard oxidation by chlorine gives permanganate as product, not manganate.
    • So this is not the best fit.

    C: MnO4−\mathrm{MnO_4^-}MnO4−​ and Cl2\mathrm{Cl_2}Cl2​

    • Matches the known reaction above.
    • Correct.

    D: MnSO4\mathrm{MnSO_4}MnSO4​ and HOCl\mathrm{HOCl}HOCl

    • MnSO4\mathrm{MnSO_4}MnSO4​ contains Mn in +2+2+2 state and does not fit the typical oxyanion interconversion suggested by the options.
    • Not correct.
  5. Therefore, X=MnO4−,Y=Cl2X = \mathrm{MnO_4^-}, \qquad Y = \mathrm{Cl_2}X=MnO4−​,Y=Cl2​

Hence, the correct option is C.

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