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Coordination Compounds question

2014 · Shift 2 · Q17
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Coordination Compounds question

2014 · Shift 2 · Q17

JEE AdvancedChemistryCoordination CompoundsMCQ+3 / −1

Match each coordination compound in List I with an appropriate pair of characteristics from List II and select the correct answer using the code given below the lists.

{en = H2NCH2CH2NH2; atomic numbers : Ti = 22, Cr = 24; Co = 27; Pt = 78}

List I List II
P. [Cr(NH3)3Cl2]Cl[Cr{(N{H_3})_3}C{l_2}]Cl[Cr(NH3​)3​Cl2​]Cl
 1. Paramagnetic and exhibits ionisation isomerism.
Q. [Ti(H2O)5Cl](NO3)2[Ti{({H_2}O)_5}Cl]{(N{O_3})_2}[Ti(H2​O)5​Cl](NO3​)2​
 2. Diamagnetic and exhibits cis-trans isomerism.
R. [Pt(en)(NH3)Cl]NO3[Pt(en)(N{H_3})Cl]N{O_3}[Pt(en)(NH3​)Cl]NO3​
 3. Paramagnetic and exhibits cis-trans isomerism.
S. [Co(NH3)4(NO3)2]NO3[Co{(N{H_3})_4}{(N{O_3})_2}]N{O_3}[Co(NH3​)4​(NO3​)2​]NO3​
 4. Diamagnetic and exhibits ionisation isomerism.

  1. A
    P-4, Q-2, R-3, S-1
  2. B
    P-3, Q-1, R-4, S-2
  3. C
    P-2, Q-1, R-3, S-4
  4. D
    P-1, Q-3, R-4, S-2
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