JEE AdvancedChemistryCoordination CompoundsNumerical+3 / −1
is ethylenediaminetetraacetate ion. The total number of N Co O bond angles in complex ion is .
Numerical answer
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Correct answer: 8
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Identify the coordination mode of
is a hexadentate ligand. It binds to the metal ion through:
- nitrogen donor atoms
- oxygen donor atoms
So in , cobalt is 6-coordinate, giving an octahedral arrangement around Co.
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Count possible bond angles
We need the number of bond angles of the type .
Since there are:
- nitrogen atoms
- oxygen atoms
each nitrogen can form an angle at Co with each oxygen.
Therefore total number of distinct angles is:
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Why no further distinction is needed
In an octahedral complex, some such angles may be and some may be , but the question asks for the total number of bond angles, not only one specific value.
Hence we count all nitrogen–cobalt–oxygen combinations.
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Final answer
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