JEE AdvancedChemistryCoordination CompoundsMCQ+3 / −1
The IUPAC name of [Ni(NH ) ] [NiCl ] is :
- ATetrachloronickel (II) - tetraamminenickel (II)
- BTetraamminenickel (II) - tetrachloronickel (II)
- CTetraammnenickel (II) - tetrachloronickelate (II)
- DTetrachloronickel (II) - tetraamminenickelate (0)
View written solutionFree
Correct answer: C
-
Identify the ions present in the compound
The compound is:
It consists of two coordination entities:
-
Find the charge and oxidation state of each complex
(i) For
- is a neutral ligand.
- So if oxidation state of Ni is , then charge on the complex is .
(ii) For
- Each has charge .
- Let oxidation state of Ni be .
- Charge on complex:
Since the overall compound is neutral, one complex must be cationic and the other anionic.
The common oxidation state here is Ni:
Check:
- In , Ni is .
- In , Ni is also because
-
Name the cation first
In naming salts, the cation is named first, then the anion.
- : ligands are ammine, so name is tetraamminenickel(II)
-
Name the anion complex
- has chloro ligands and is an anionic complex, so metal name ends in -ate.
- Therefore its name is tetrachloronickelate(II)
-
Write the full IUPAC name
is named: tetraamminenickel(II) tetrachloronickelate(II)
-
Match with the given options
- A: Wrong order and anion not written as nickelate
- B: Anion should be nickelate, not nickel
- C: Correct
- D: Wrong oxidation state and wrong naming
Therefore, the correct option is C.
More from Coordination Compounds
- Match the complexes in Column I with their properties listed in Column II. Indicate your answer by darkening the appropriate bubbles of the 4 4 matrix given in the ORS. Includes table2007 · MCQ
- Among the following metal carbonyl, the C-O bond order is lowest in2007 · MCQ
- The correct order of the wavelength maxima of the absorption band in the ultraviolet-visible region for the given complexes is2025 · MCQ
- The sum of the spin only magnetic moment values (in B.M.) of and is .2025 · Numerical
- Among ,…2024 · Numerical
- Among the following complexes, the total number of diamagnetic species is . …2024 · Numerical
- Among the following options, select the option in which each complex in Set-I shows geometrical isomerism and the two complexes in Set-II are ionization isomers of each other. …2024 · MCQ
- Among …2024 · Numerical