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Chemical Kinetics and Nuclear Chemistry question

2019 · Shift 1 · Q7
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Chemical Kinetics and Nuclear Chemistry question

2019 · Shift 1 · Q7

JEE AdvancedChemistryChemical Kinetics and Nuclear ChemistryMultiple correct+4 / −1
In the decay sequence. JEE Advanced 2019 Paper 1 Offline Chemistry - Chemical Kinetics and Nuclear Chemistry Question 18 English x1, x2, x3 and x4 are particles/radiation emitted by the respective isotopes. The correct option(s) is(are)
  1. A
    Z is an isotope of uranium
  2. B
    x2 is β\betaβ-
  3. C
    x1 will deflect towards negatively charged plate
  4. D
    x3 is γ\gammaγ-ray
View written solutionFree

Correct answer: A, B, C

  1. Use the standard changes in radioactive emissions

    • For an α\alphaα-particle emission: A→A−4,Z→Z−2A \to A-4, \quad Z \to Z-2A→A−4,Z→Z−2
    • For a β−\beta^-β−-particle emission: A→A,Z→Z+1A \to A, \quad Z \to Z+1A→A,Z→Z+1
    • For a γ\gammaγ-ray emission: A→A,Z→ZA \to A, \quad Z \to ZA→A,Z→Z
  2. Analyze the given decay sequence qualitatively

    From the decay chain, the emitted species are labeled x1,x2,x3,x4x_1, x_2, x_3, x_4x1​,x2​,x3​,x4​.

    From the nuclear changes shown in the sequence:

    • The first step decreases mass number by 444 and atomic number by 222, so x1=αx_1 = \alphax1​=α
    • The second step keeps mass number same and increases atomic number by 111, so x2=β−x_2 = \beta^-x2​=β−
    • The third step does not correspond to a pure γ\gammaγ transition, so x3≠γx_3 \neq \gammax3​=γ
  3. Check each option

    Option A: ZZZ is an isotope of uranium

    Uranium has atomic number 929292. From the final nucleus shown in the sequence, ZZZ has atomic number 929292. Hence this is correct.

    Option B: x2x_2x2​ is β−\beta^-β−

    As seen above, the second transition has: ΔA=0,ΔZ=+1\Delta A = 0, \quad \Delta Z = +1ΔA=0,ΔZ=+1 which is characteristic of β−\beta^-β− emission. Hence correct.

    Option C: x1x_1x1​ will deflect towards negatively charged plate

    Since x1=αx_1 = \alphax1​=α, it carries charge +2+2+2. A positively charged particle deflects toward the negatively charged plate. Hence correct.

    Option D: x3x_3x3​ is γ\gammaγ-ray

    x3x_3x3​ is not a γ\gammaγ transition from the nuclear changes in the sequence. Hence incorrect.

  4. Final answer

    The correct options are: A, B, C\boxed{A,\ B,\ C}A, B, C​

  5. Comparison with stored correct answer

    Stored correct answer: A,B,CA, B, CA,B,C

    This matches the derived answer.

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