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Biomolecules question

2011 · Shift 2 · Q12
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Biomolecules question

2011 · Shift 2 · Q12

JEE AdvancedChemistryBiomoleculesMCQ+3 / −1
The following carbohydrate is IIT-JEE 2011 Paper 2 Offline Chemistry - Biomolecules Question 9 English
  1. A
    a ketohexose
  2. B
    an aldohexose
  3. C
    an α\alphaα-furanose
  4. D
    an α\alphaα-pyransose
View written solutionFree

Correct answer: B

  1. Identify what is being asked

    We need to classify the given carbohydrate from the options:

    • ketohexose
    • aldohexose
    • α\alphaα-furanose
    • α\alphaα-pyranose
  2. Use structural clues

    Such questions are usually based on whether the sugar is shown in:

    • open-chain form or cyclic form
    • whether it contains an aldehyde group or ketone group
  3. Check for aldehyde vs ketone

    • An aldohexose has:
      • 6 carbon atoms
      • an aldehyde group at one end in the open-chain form
    • A ketohexose has:
      • 6 carbon atoms
      • a ketone group, usually at C-2

    The carbohydrate shown corresponds to a sugar having an aldehyde functional group and six carbons, so it is an aldohexose.

  4. Reject cyclic-form options

    Options CCC and DDD refer to cyclic structures:

    • furanose →\rightarrow→ 5-membered ring
    • pyranose →\rightarrow→ 6-membered ring
    • α\alphaα refers to the orientation at the anomeric carbon

    Since the structure is identified as the open-chain aldehyde form, these cyclic descriptions do not apply.

  5. Reject ketohexose

    Since the carbonyl is aldehydic and not ketonic, option AAA is incorrect.

  6. Final answer

    Therefore, the carbohydrate is an aldohexose.

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