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Organic Compounds Containing Nitrogen

50 questions · Chemistry · NEET
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Organic Compounds Containing Nitrogen

50 questions · Chemistry · NEET

  1. The correct order of decreasing basic strength of the given amines is: Answer (1) Sol. Lower is the value of pKb​, higher is the basicity Also aliphatic amines are stronger bases than aromatic amines. pKb​…2025 · Q124 · MCQ
  2. Given below are two statements : Statement-I : Benzenediazonium salt is prepared by the reaction of aniline with nitrous acid at 273−278 K. It decomposes easily in the dry state. Statement-II : Insertion of iodine into the…2025 · Q134 · MCQ
  3. Given below are two statements: Statement I : Aniline does not undergo Friedel-Crafts alkylation reaction. Statement II : Aniline cannot be prepared through Gabriel synthesis. In the light of the above statements, choose the correct answer…2024 · Q112 · MCQ
  4. The major product X formed in the following reaction sequence is : Includes diagram2024 · Q106 · MCQ
  5. The compound that does not undergo Friedel-Crafts alkylation reaction but gives a positive carbylamine test is :2024 · Q128 · MCQ
  6. Identify the product in the following reaction: Includes diagram2023 · Q100 · MCQ
  7. Which of the following reactions will NOT give primary amine as the product?2023 · Q109 · MCQ
  8. The product formed from the following reaction sequence is : Includes diagram2022 · Q110 · MCQ
  9. Which of the following sequence of reactions is suitable to synthesize chlorobenzene?2022 · Q103 · MCQ
  10. Given below are two statements Statement I : Primary aliphatic amines react with HNO2 to give unstable diazonium salts. Statement II : Primary aromatic amines react with HNO2 to form diazonium salts which are stable even above 300 K. In…2022 · Q108 · MCQ
  11. The product formed from the following reaction sequence is Includes diagram2022 · Q121 · MCQ
  12. Identify the compound that will react with Hinsberg's reagent to give a solid which dissolves in alkali.2021 · Q102 · MCQ
  13. Which of the following amine will give the carbylamine test?2020 · Q110 · MCQ
  14. The correct order of the basic strength of methyl substituted amines in aqueous solution is :2019 · Q90 · MCQ
  15. The major product of the following reaction is : Includes diagram2019 · Q93 · MCQ
  16. Nitration of aniline in strong acidic medium also gives m-nitroaniline because2018 · Q95 · MCQ
  17. Which of the following reactions is appropriate for converting acetamide to methanamine?2017 · Q86 · MCQ
  18. The correct increasing order of basic strength for the following compounds is Includes diagram2017 · Q95 · MCQ
  19. The correct statement regarding the basicity of arylamines is2016 · Q116 · MCQ
  20. The product formed by the reaction of an aldehyde with a primary amine is2016 · Q117 · MCQ
  21. Which one of the following nitro-compounds does not react with nitrous acid?2016 · Q83 · MCQ
  22. A given nitrogen-containing aromatic compound 'A' reacts with Sn/HCl, followed by HNO2 to give instable compound 'B'. 'B', on treatment with phenol, forms a beautiful coloured compound 'C' with the molecular formula C12H10N2O. The…2016 · Q84 · MCQ
  23. The following reaction is known by the name Includes diagram2015 · Q78 · MCQ
  24. Method by which aniline cannot be prepared is2015 · Q79 · MCQ
  25. The number of structural isomers possible from the molecular formula C3H9N is2015 · Q80 · MCQ
  26. The electrolytic reduction of nitrobenzene in strongly acidic medium produces2015 · Q80 · MCQ
  27. In the following reaction, the product (A) is Includes diagram2014 · Q86 · MCQ
  28. Which of the following will be most stable diazonium salt RN2+X−?2014 · Q87 · MCQ
  29. On hydrolysis of a ''compound'', two compounds are obtained. One of which one treatment with sodium nitrite and hydrochloric acid gives a product which does not respond to iodoform test. The second one reduces Tollens reagent and Fehling's…2013 · Q84 · MCQ
  30. Some reactions of amines are given. Which one is not correct?2013 · Q85 · MCQ
  31. Nitrobenzene on reaction with conc. HNO3/H2SO4 at 80−100oC forms which one of the following products?2013 · Q120 · MCQ
  32. In the reaction A is Includes diagram2013 · Q92 · MCQ
  33. An organic compound (C3H9N) (A), when treated with nitrous acid, gave an alcohol and N2 gas was evolved. (A) on warming with CHCl3 and caustic potash gave (C) which on reduction gave isopropylmethylamine. Predict the structure of (A)2012 · Q70 · MCQ
  34. What of the following compounds is most basic?2011 · Q69 · MCQ
  35. What is the product obtained in the following reaction? Includes diagram2011 · Q89 · MCQ
  36. Which of the following statements about primary amines is false?2010 · Q100 · MCQ
  37. Aniline in a set of the following reactions yielded a coloured product Y. The structure of 'Y' would be Includes diagram2010 · Q101 · MCQ
  38. Acetamide is treated with the following reagents separately. Which one of these would yield methyl amine?2010 · Q97 · MCQ
  39. Nitrobenzene can be prepared from benzene by using a mixture of conc. HNO3 and conc. H2SO4. In the mixture, nitric acid acts as a/an2009 · Q92 · MCQ
  40. Predict the product. Includes diagram2009 · Q93 · MCQ
  41. In a reaction of aniline a coloured product C was obtained. The structure of C would be Includes diagram2008 · Q93 · MCQ
  42. Which one of the following on reduction with lithium aluminium hydride yields a secondary amine?2007 · Q80 · MCQ
  43. Which of the following is more basic than aniline?2006 · Q89 · MCQ
  44. Electrolytic reduction of nitrobenzene in weakly acidic medium gives2005 · Q128 · MCQ
  45. Aniline in a set of reactions yielded a product D. The structure of the product D would be Includes diagram2005 · Q95 · MCQ
  46. In a reaction of aniline a coloured product C was obtained. The structure of C would be Includes diagram2004 · Q82 · MCQ
  47. The final product C, obtained in this reaction would be Includes diagram2003 · Q95 · MCQ
  48. Product 'P' in the above reaction is Includes diagram2002 · Q92 · MCQ
  49. Intermediates formed during reaction of are Includes diagram2001 · Q90 · MCQ
  50. then A is Includes diagram2000 · Q89 · MCQ