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Organic Compounds Containing Nitrogen question

2013 · Q84
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Organic Compounds Containing Nitrogen question

2013 · Q84

NEETChemistryOrganic Compounds Containing NitrogenMCQ+4 / −1
On hydrolysis of a ''compound'', two compounds are obtained. One of which one treatment with sodium nitrite and hydrochloric acid gives a product which does not respond to iodoform test. The second one reduces Tollens reagent and Fehling's solution. The ''compound'' is
  1. A
    CH3CH2CH2NC
  2. B
    CH3CH2CH2CN
  3. C
    CH3CH2CH2ON === O
  4. D
    CH3CH2CH2CON(CH3)2
View written solutionFree

Correct answer: A

Hydrolysis of propyl isocyanide (CH3CH2CH2NC) gives CH3CH2CH2NH2 + HCOOH.

On treatment with NaNO2 and HCl I(CH3CH2CH2NH2) gives CH3CH2CH2OH which does not give iodoform test. II (HCOOH) reduces Tollen’s reagent and Fehling’s solution.

NEET 2013 (Karnataka) Chemistry - Organic Compounds Containing Nitrogen Question 35 English Explanation

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