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Organic Compounds Containing Nitrogen question

2018 · Q95
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Organic Compounds Containing Nitrogen question

2018 · Q95

NEETChemistryOrganic Compounds Containing NitrogenMCQ+4 / −1
Nitration of aniline in strong acidic medium also gives m-nitroaniline because
  1. A
    inspite of substituents nitro group always goes to only m-position
  2. B
    in electrophilic substitution reactions amino group is meta directive
  3. C
    in absence of substituents nitro group always goes to m-position
  4. D
    in acidic (strong) medium aniline is present as anilinium ion.
View written solutionFree

Correct answer: D

NEET 2018 Chemistry - Organic Compounds Containing Nitrogen Question 14 English Explanation
In acidic medium, aniline is protonated to form anilinium ion which is m-directing. Hence besides para (51%) and ortho (2%), meta product (47%) is also formed in significant yield.
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