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Coordination Compounds question

2024 · Q115
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Coordination Compounds question

2024 · Q115

NEETChemistryCoordination CompoundsMCQ+4 / −1

Match List I with List II.

List I
(Complex)
List II
(Type of isomerism)
A. $$
[Co(NH3)5(NO2)]Cl2\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{NO}_2\right)\right] \mathrm{Cl}_2[Co(NH3​)5​(NO2​)]Cl2​
$$
I. Solvate isomerism
B. $$
[Co(NH3)5(SO4)]Br\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Br}[Co(NH3​)5​(SO4​)]Br
$$
II. Linkage isomerism
C. $$
[Co(NH3)6][Cr(CN)6]\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Cr}(\mathrm{CN})_6\right][Co(NH3​)6​][Cr(CN)6​]
$$
III. Ionization isomerism
D. $$
[Co(H2O)6]Cl3\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3[Co(H2​O)6​]Cl3​
$$
IV. Coordination isomerism

Choose the correct answer from the options given below:

  1. A
    A-II, B-III, C-IV, D-I
  2. B
    A-I, B-III, C-IV, D-II
  3. C
    A-I, B-IV, C-III, D-II
  4. D
    A-II, B-IV, C-III, D-I
View written solutionFree

Correct answer: A

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A.$$
\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{NO}_2\right)\right] \mathrm{Cl}_2
$$
I.Linkage isomerism due to 'N' and 'O' linkage by NO$_2$
B.$$
\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Br}
$$
II.Ionization isomerism
C.$$
\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Cr}(\mathrm{CN})_6\right]
$$
III.Coordination isomerism
D.$$
\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3
$$
IV.Solvate isomerism
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