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Coordination Compounds question

2023 · Q115
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Coordination Compounds question

2023 · Q115

NEETChemistryCoordination CompoundsMCQ+4 / −1

Type of isomerism exhibited by compounds [Cr(H2O)6Cl3,[Cr(H2O)5Cl2Cl2⋅H2O,[Cr(H2O)4Cl2]Cl.2H2O\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6 \mathrm{Cl}_3,\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{Cl}_2 \mathrm{Cl}_2 \cdot \mathrm{H}_2 \mathrm{O}\right.\right.,\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_4 \mathrm{Cl}_2\right] \mathrm{Cl} .2 \mathrm{H}_2 \mathrm{O}[Cr(H2​O)6​Cl3​,[Cr(H2​O)5​Cl2​Cl2​⋅H2​O,[Cr(H2​O)4​Cl2​]Cl.2H2​O and the value of coordination number (CN)(\mathrm{CN})(CN) of central metal ion in all these compounds, respectively is :

  1. A
    Geometrical isomerism, CN = 2
  2. B
    Optical isomerism, CN = 4
  3. C
    Ionisation isomerism, CN = 4
  4. D
    Solvate isomerism, CN = 6
View written solutionFree

Correct answer: D

Given complex compounds exhibit solvate isomerism having co-ordination number = 6.

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